我国土壤重金属污染问题已成为环境污染的热点问题。以柠檬酸和草酸作为萃取剂,采用态浸提的方式探讨萃取剂/土壤比例(酸土比)和萃取时间对土壤中Pb、Zn的去除效率和稳定效率的影响。研究结果显示:1)柠檬酸、草酸的最佳酸土比分别为10%和5%。2)柠檬酸和草酸通过改变重金属在土壤中的存在形态达到修复的目的。3)柠檬酸和草酸对Pb和Zn的静态浸取时间分别为10 d和5 d。柠檬酸和草酸对重金属Pb和Zn的静态浸取过程遵循改进后的一级反应动力学方程。
In China,heavy metals contamination in soils has become a serious environmental issue. In this paper,oxalic acid and citric acid were used as extracting agents to extract lead( Pb) and zinc( Zn) from soils in a static way. The effects of extracting agent / soil weight ratio( acid / soil ratio) and extraction time on removal rate and stabilization efficiency were studied. Results showed that: 1) The most suitable acid / soil ratio for oxalic acid and citric acid were 10% and 5%,respectively; 2) both oxalic acid and citric acid transformed the forms of Pb and Zn in soils to repair soil; 3) the best static extraction time for Pb and Zn by oxalic acid and citric acid was 10 d and 5 d,respectively. The static extraction kinetics of Pb and Zn by oxalic acid and citric acid fit well with the modified one-order reaction kinetics equation.