采用高温固相法制备了LiSrBO3:xEu3+荧光粉,并通过X射线衍射,红外和荧光光谱等对其表征.结果表明,LiSrBO3:Eu3+荧光粉可被波长为395nm的紫外线和466nm的蓝光有效激发,且发射主波长为612nm(Eu3+的电偶极跃迁5D0→7F2)的红光.研究了Eu3+掺杂浓度对LiSrBO3:Eu3+材料发光强度的影响,Eu3+掺杂浓度为6%时样品的发射强度最大,并且证实Eu3+之间的能量传递机制为电偶极子-电偶极子相互作用.Li+,Na+,K+作为电荷补偿剂的引入全部导致LiSrBO3:Eu3+材料发射强度增强,其中,Li+的引入要优于Na+和K+.少量Al3+的掺杂降低了Eu3+所处格位的对称性,增强了Eu3+的612nm的电偶极发射,改善了LiSrBO3:Eu3+红色材料的色纯度.
LiSrBO3:xEu3+ phosphors were synthesized by conventional solid-state reaction and were systematically characterized by powder X-ray diffraction,Fourier transform infrared spectroscopy and photoluminescence spectroscopy.The excitation and emission spectra reveal that the LiSrBO3:Eu3+ phosphor can be effectively excited by ultraviolet(395 nm)and blue(466 nm)light and exhibits a satisfactory red performance which peaked at around 612 nm corresponding to the 5D0 → 7F2 transitions of Eu3+.The concentration quenching mechanism was verified to be a dipole-dipole interaction.The dopant R+(R+ = Li+,Na+ and K+)as charge compensator can further enhance luminescence intensity,and the emission intensity of the phosphor doped with Li+ is higher than that doped with Na+ or K+.Introduction of Al3+ reduced the symmetry of the crystal field and increased the emission of 612 nm(5D0 → 7F2),which improved the chromaticity coordinates of LiSrBO3:Eu3+ phosphor.