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脲醛预聚条件对电泳微胶囊形态的影响
  • 期刊名称:过程工程学报,2006,6(1):51-54. (EI)
  • 时间:0
  • 分类:O631[理学—高分子化学;理学—化学]
  • 作者机构:[1]中国科学院理化技术研究所,北京100101, [2]哈尔滨工程大学材料学院,黑龙江哈尔滨150001, [3]中国科学院研究生院,北京100049
  • 相关基金:国家863计划资助项目(编号:2004AA302012):国家自然科学基金资助项目(编号:No.60572031)
  • 相关项目:仿生红外发射调变原理研究
中文摘要:

以尿素和甲醛为壁材,油性蓝和二氧化钛纳米粒子分散在四氯乙烯中作为囊芯,通过原位聚合法制备了电泳微胶囊.研究了脲醛预聚体制备条件对微胶囊形成和产品形态的影响,并通过设计正交实验得到了最优化的制备条件,即脲:甲醛为1:1.75(摩尔比),反应温度75℃,pH值8.5,反应时间1h.在最优化条件下制备出的电泳微胶囊内外表面光滑,囊壁透明,分散性好且形态完整.

英文摘要:

Electrophoretic microcapsules were prepared via in-situ interfacial polymerization using ureaformaldehyde (UF) resin as the outer membrane and oil blue and TiO2 nanoparticles dispersed in tetrachloroethylene as core materials. The effects of reaction conditions for the synthesis of UF prepolymer on the morphology of microcapsules were investigated and the optimal reaction conditions were obtained by the orthogonal design. The results showed that the optimum reaction conditions were molar ratio of urea to formaldehyde 1:1.75, reaction temperature 75 ℃, pH 8.5 and reaction time 1 h. The electrophoretic microcapsules prepared with such conditions had many merits, such as smooth inner and outer surface, transparence, good dispersity and complete morphology, etc.

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