中文摘要：

三新建筑群，[ Zn ( dtb )( 4,4 ′-bipy )] ·5 H ₂ O ( 1 )，[ Zn ( dtb )( bpp )] ·H ₂ O ( 2 )并且[ Zn ( dtb )( phen ) ₂]·CH₃-CH₂哦 ·H ₂ O ( 3 )( dtb = 5,5 ′-dithiobis ( 2-nitrobenzoic 酸)， 4,4 ′-bipy = 4,4 ′-bipyridine ， bpp =1,3双性人( 4-pyridyl )丙烷， phen = 1,10-phenanthroline )，被 dtb ligand 和锌盐在热水的条件下面面对不同助理 包含N ligands 构造了。建筑群的结构被单个水晶的 X 光检查衍射分析建立。尽管 1 和 2 两个都是的混合物螺旋的 2D 网络，洞的形式和程度是不同的。化合物 3 的结构显示出 1D 螺旋状由超级分子相互作用锁住，并且被扩大进一个 2D 框架。这些中立聚合建筑群由于灵活 dtb ligand 的不同协作模式和助理 ligands 的效果展出结构、维的差异。

英文摘要：

Three new complexes, [Zn（dtb）（4,4′-bipy）]·5H2O （1）, [Zn（dtb）（bpp）]·H2O （2） and [Zn（dtb）（phen）2]·CH3- CH2OH·H2O （3） （dtb = 5,5′-dithiobis（2-nitrobenzoic acid）, 4,4′-bipy = 4,4′-bipyridine, bpp = 1,3-bi（4-pyridyl） propane, phen = 1,10-phenanthroline）, have been constructed by dtb ligand and zinc salt in the presence of different assistant N-containing ligands under hydrothermal conditions. The structures of the complexes were established by single-crystal X-ray diffraction analysis. Although compounds 1 and 2 are both 2D networks, the cavities＇ forms and pitch of helix are different. The structure of compound 3 shows a 1D helical chain, and is extended by the supermolecule interactions into a 2D framework. These neutral polymeric complexes exhibit structural and dimensional diversity due to the different coordination modes of the flexible dtb ligand and the effect of assistant ligands.