位置:成果数据库 > 期刊 > 期刊详情页
不同养护温度下含白云石和石灰石微粉砂浆的孔结构
  • ISSN号:0454-5648
  • 期刊名称:《硅酸盐学报》
  • 时间:0
  • 分类:TQ172[化学工程—水泥工业;化学工程—硅酸盐工业]
  • 作者机构:南京工业大学材料科学与工程学院,南京210009
  • 相关基金:国家自然科学基金资助项目(51472116).
中文摘要:

以石灰石微粉(LS)为参照,研究了20、40℃和60℃养护时10%和30%掺量白云石微粉(DM)对水泥砂浆强度的影响,并采用压汞法(MIP)研究了混合水泥砂浆的孔结构。结果表明:20℃和40℃时,LS优于DM促进早期强度发展,但两者差异随掺量增加和龄期延长而减小。提高温度到60℃,对DM砂浆各龄期强度的促进效应均比对LS体系更为显著,且掺量愈大,两者对温度效应的差异愈明显。三种养护温度下,DM与LS的掺入均增加砂浆孔隙率,且掺量愈大孔隙率愈大。10%掺量时,DM与LS对孔径分布影响不大,而30%掺量时两者均明显粗化孔径。与LS相比,20℃时,DM砂浆孔隙率大于LS砂浆,孔径粗化也更为明显;40℃时,DM砂浆孔隙率近似或小于LS砂浆,两者孔径分布类似;继续提高温度到60℃,DM砂浆孔隙率小于LS砂浆,孔径分布优于LS砂浆,且掺量愈大两者差异愈明显。提高养护温度,对DM砂浆孔结构的劣化效应弱于LS砂浆。DM的化学活性对升高温度的响应强于LS,DM反应生成的水滑石利于降低孔隙率并改善孔径分布,促进水泥砂浆强度发展。

英文摘要:

Strength of blended cements mortars with dolomite powder (DM) at different replaced contents, i.e., 10% and 30%, and cured at 20, 40 ℃ and 60 ℃ were investigated. Limestone powder (LS) was also used for the comparison. The pore structure of blended cements mortars were examined by mercury intrusion porosimetry (MIP). The results indicate that DM and LS have different effects on the mortar strength at various replacement levels and curing temperatures. At 20 ℃ and 40 ℃, LS shows more positive impact on the promotion of the early strength, compared to DM, but this difference decreases with the increase of replacement level and the curing age. Compared to the mortars with LS, increasing the curing temperature to 60 ℃ gives a stronger promoting effect on the strength of mortars with DM, and the effect is more pronounced with the increase of replacement levels. With the incorporation of dolomite or limestone powders, the porosity of mortars increases. At the replacement level of 10%, DM and LS show similar effects on the pore size distribution of mortars. Compared to the mortars with LS, the mortars with DM cured at 20 ℃ have a greater porosities and larger pore sizes. When cured at 40 ℃, the mortars with DM and LS develop the similar porosity and pore size distribution. When the curing temperature is 60 ℃, the mortars with DM show a lower porosity and better pore size distribution, compared to the mortars with LS. DM gives a superior effect on the pore structure of mortars when the curing temperature increases. DM develops a stronger chemical effect at high curingtemperatures and results in the formation of hydrotalcite, which is beneficial to decreasing the porosity, improving the pore structure and promoting the strength of cement mortars.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《硅酸盐学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国硅酸盐学会
  • 主编:南策文
  • 地址:北京海淀区三里河路11号
  • 邮编:100831
  • 邮箱:jccsoc@sina.com
  • 电话:010-57811253 57811254
  • 国际标准刊号:ISSN:0454-5648
  • 国内统一刊号:ISSN:11-2310/TQ
  • 邮发代号:2-695
  • 获奖情况:
  • EI Compendex、CA、SA、PI收录期刊,全国核心期刊,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:27713