欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以无水三氯化铁为催化剂前驱体,乙烯为碳源,采用浮游催化法成功大量合成铁填充型碳纳米管。系统地考察了催化剂输入浓度及载气种类对产物的影响。利用环境扫描电子显微镜、透射电子显微镜、X-射线衍射、拉曼光谱和振动磁强计等多种技术手段对产物进行了表征。结果表明：三氯化铁可以替代传统上惯用的有机金属化合物二茂铁作为催化剂前驱体,具有廉价、可控性好等优点,得到的碳纳米管内腔填充有连续的Fe纳米线;这些Fe填充纳米管具有超顺磁性。
英文摘要：
Large-scale in-situ synthesis of Fe-filled carbon nanotubes was achieved by chemical vapor deposition （CVD） with anhydrous FeCl3 as floating catalyst precursor and ethylene as carbon source. The effects of catalyst and carrier gas were studied. The as-grown products were characterized using SEM, TEM, XRD, Raman, and vibrating sample magnetometer techniques. It has been found that for the floating CVD technique, anhydrous FeCl3 is a good yet cheap catalyst precursor that is better than the traditional ferrocene catalyst in terms of the purity and filling ratio of the Fe-filled carbon nanotubes produced. The superparamagnetic property of the carbon nanotubes was also demonstrated by vibrating sample magnetometry.
同期刊论文项目
同项目期刊论文
In situ formation of N,O-bidentate ligand via the hydrogen bond for highly efficient Suzuki reaction
Aerobic oxidation of alcohols over carbon nanotube-supported Ru catalysts assembled at the interface
Effects of carbonization conditions on the properties of coal-based microfiltration carbon membranes
Sidewall fluorination and hydrogenation of single-walled carbon nanotubes: a density functional theo
In-situ synthesis of Fe-filled carbon nanotubes by a floating CVD method with FeCl3 as catalyst prec
Effect of CNT Surface Modification on Catalytic Performance of Pt/CNT for Selective Hydrogenation of
Fabrication of carbon nanofibres and bamboo-shaped carbon nanotubes with open ends from anthracite c
Tailoring of three-dimensional carbon nanotube architectures by coupling capillarity-induced assembl
Very Fast, Ligand-Free and Aerobic Protocol for the Synthesis of 4-Aryl-Substituted Triphenylamine D
A simple and efficient protocol for a palladium-catalyzed ligand-free Suzuki reaction at room temper
A new approach to high performance Co/C catalysts for selective hydrogenation of chloronitrobenzenes
Carbon dioxide-assisted fabrication of self-organized tubular carbon micropatterns on silicon substr
A facile approach to simultaneous fabrication of microsize hollow and. solid carbon spheres from ace
Increasing the shell thickness by controlling the core size of zeolite capsule catalyst: Application
Investigation of the Role of Surface Chemistry and Accessibility of Cadmium Adsorption Sites on Open
Aerobic oxidation of alcohols over Au/TiO2: An insight on the promotion effect of water on the catal
Preparation of nanoscale CexFe1-xO2 solid solution catalyst by the template method and its catalytic
期刊信息
位置：