研究不同水灰比条件下的钢纤维增强水泥基复合材料界面过渡区(ITZ)的纳米力学性能。通过纳米压痕试验,测试界面过渡区及其附近区域的荷载-压痕深度曲线,运用Oliver-Pharr方法研究了弹性模量和硬度分布规律并绘制相应的微结构表征云图,结合扫描电子显微镜分析ITZ形成机制。此外,利用反褶积法对ITZ的弹性模量及压痕硬度的频率分布曲线进行多峰拟合,得到了各相的频率分布。结果表明:不同水灰比样品界面过渡区的厚度均为40μm左右;在界面过渡区内,弹性模量和压痕硬度的最弱点在距纤维表面20μm附近,且水灰比越大,弹性模量与压痕硬度值越小;随着水灰比的增大,界面过渡区孔洞和低密度水化硅酸钙含量逐渐增高,高密度水化硅酸钙含量逐渐降低。
The nanoscale mechanical properties of interfacial transition zone (ITZ) in steel fiber reinforced cementitious composite for different water-cement ratios were investigated. The load-crack depth (P-h) curves of ITZ were determined via nanoindentation test. The distribution of elastic modulus and hardness were calculated and mapped in a 2D plane by the Oliver-Pharr method. The formation mechanism of ITZ was analyzed. In addition, the frequency distribution of different phases in ITZ was determined by a multi-peak fitting deconvolution method. The results indicate that there is a interface width about 40 pxn in all the cases. The minimum modulus and hardness occur at a distance of 20 ~tm from the steel fiber surface. The greater the water-cement ratio, the lower elastic modulus and hardness will be. The content of porosity and low density C-S-H gradually increase, and the density of C-S-H decreases with the increase of water-cement ratio.