以溶胶凝胶方法制备的SiO2修饰的碳纳米管(SiO2-CNTs)为载体材料,利用微波辅助加热化学还原方法制备了Pt-SiO2-CNTs纳米催化剂.分别利用扫描电子显微镜和能量散射谱仪对Pt-SiO2-CNTs纳米颗粒的表面形貌和元素组成进行了表征.在酸性介质中,通过循环伏安法研究了Pt-SiO2-CNTs纳米催化剂对乙醇氧化的电催化性能.与商用催化剂PtRu/C(E-TEK)相比,在相同的催化剂栽量和实验条件下,Pt-SiO2-CNTs催化剂比PtRu/C(E-TEK)催化剂对乙醇氧化具有更好的催化活性和抗CO中毒能力.
SiO2 modified carbon nanotubes were prepared through sot-gel method and used as the catalyst support. The Pt-SiO2 -CNTs nanocatalyst was synthesized in microwave-assisted chemical reduction method. The micrography and elemental composition of Pt-SiO2-CNTs nanoparticles were characterized by scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. The electrocatalytie properties of Pt -SiO2-GNTs nanocatalysts for ethanol oxidation were investigated with cyclic voltammetry in acidic solution. Under the same catalyst loading mass and experimental conditions, Pt-SiO2 --CNTs nanocatalysts have shown higher electroeatalytie activity than PtRu/C (E-TEK) catalyst. In addition, Pt-SiO2-CNTs nanocatalysts pos- sess good anti-poisoning ability.