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AC/PTFE微生物燃料电池阴极去除罗丹明B及同步产电性能
  • ISSN号:1673-9108
  • 期刊名称:《环境工程学报》
  • 时间:0
  • 分类:X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]东华大学环境科学与工程学院,上海201620, [2]湖南省怀化市环境保护监测站,怀化418000, [3]上海市青浦区环境监测站,上海201700
  • 相关基金:国家自然科学基金资助项目(21477018,21007010); 交通运输部科技项目(2010353343290)
中文摘要:

采用辊压成型法制备了活性炭(AC)/聚四氟乙烯(PTFE)质量比分别为6、5和3的AC/PTFE电极,并利用SEM对电极表面进行表征。结果表明,随着质量比的降低电极表面活性炭颗粒间的连接更为紧密。以制得的AC/PTFE电极,碳毡分别为微生物燃料电池(MFC)的阴极、阳极,利用AC/PTFE阴极在曝气条件下产生的过氧化氢在阴极处理模拟的罗丹明B废水。研究了不同质量比AC/PTFE阴极对罗丹明B的去除效果及同步产电情况,结果表明以AC/PTFE质量比为6的AC/PTFE阴极在96 h内对罗丹明B的去除率达到96%,MFC获得的最大功率密度为105 mW·m~(-2);同时研究了在阴极液加入0.2 g·L-1Fe~(2+)的条件下,阴极液为不同pH值时,阴极对罗丹明B的去除效果及MFC产电情况。结果表明在阴极液pH=3的情况下,罗丹明B的去除率在36 h内达到了98.9%,MFC的最大功率密度达到210 mW·m~(-2),罗丹明B的去除速率及MFC能量的输出得到了明显提高。

英文摘要:

An activated carbon / polytetrafluoroethylene( AC / PTFE) electrode was prepared under pressure with mass ratios of 6 ∶ 1,5 ∶ 1,and 3 ∶ 1,and the resulting electrodes were characterized by scanning electron microscopy( SEM). The number of cross-linked electrode networks were reduced with an increase in AC / PTFE ratio. A two-chambered microbial fuel cell( MFC) equipped with carbon felt anode and the as-prepared AC / PTFE cathode was constructed to treat Rhodamine B( Rh B) in the cathodic chamber by reaction with hydrogen peroxide generated at the aerated AC / PTFE cathode. The simultaneous reaction / removal of Rh B and electricity generation of the MFC was studied using various AC / PTFE mass ratios. The Rh B decolorization efficiency reached96% over 96 h,and generated a maximum power density of 105 m W·m-2when the MFC was equipped with an AC / PTFE cathode with a mass ratio of 6 ∶ 1. The simultaneous reaction / removal of Rh B and MFC electricity generation was also studied with the addition of 0. 2 g ·L-1Fe2 +to the catholyte at different pH values. The Rh B decolorization efficiency reached 98. 9% over 36 h due to the bio-electro-Fenton reaction with a catholyte pH of 3. Under these conditions,the MFC generated a maximum power density of 210 m W·m-2,thus confirming that Rh B decolorization and MFC electricity generation improved significantly.

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期刊信息
  • 《环境工程学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:曲久辉
  • 地址:北京东黄城根北街16号
  • 邮编:100017
  • 邮箱:
  • 电话:010-62941074
  • 国际标准刊号:ISSN:1673-9108
  • 国内统一刊号:ISSN:11-5591/X
  • 邮发代号:82-448
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘
  • 被引量:20083