中文摘要：

一系列 lanthanide 建筑群[行( 4-Cl-2-MOBA )<潜水艇class=“ a-plus-plus ”> 3 phen ]<潜水艇class=“ a-plus-plus ”> 2 ( Ln=Sm ( 1 )， Nd ( 2 )，惊讶( 3 )， Eu ( 4 )， Dy ( 5 )，和 Tb ( 6 )；4-Cl-2-MOBA=4-chloro-2-methoxybenzoate， phen=1,10-phenanthroline ) 被综合并且描绘。单个水晶的 X 光检查衍射证明 13 是同态的，它作为衔接 ligands 与四 4-Cl-2-MOBA 阴离子功能介绍二聚的结构。1 和 46 显示的建筑群他们中央行的典型的光排放乐队 < 啜 class= “ a-plus-plus ” >3+ 个 离子。热能力，热力学的功能和 thermogravimetryFourier 转变建筑群的气体的产品的红外线的系列 16 被调查。他们第二个分解阶段的非等温的动力学被不可分的 isoconversional 学习非线性的方法和空方法。而且， 16 对 Candida albicans， Escherichia coli 和葡萄球菌 aureu 展出了优秀抗菌剂活动。

英文摘要：

A series of lanthanide complexes [Ln（4-Cl-2- MOBA）3phen]2 （Ln=Sm （1）, Nd （2）, Ho （3）, Eu （4）, Dy （5）, and Tb （6）; 4-Cl-2-MOBA=4-chloro-2-methoxybenzoate, phen=1,10-phenanthroline） were synthesized and characterized. The single-crystal X-ray diffraction demonstrates that 1-3 are isomorphous, which present dimeric structures with four 4-Cl-2-MOBA anions function as bridging ligands. Complexes 1 and 4-6 display their characteristic luminescence emission bands of central Ln^3＋ ions. The heat capacities, the thermodynamic functions and the thermogravimetry-Fourier transform infrared spectra of gaseous products of complexes 1-6 were investigated. Their non-isothermal kinetics of the second decomposition stage was studied by the integral isoconversional non-linear method and Stark method. Furthermore, 1-6 exhibited excellent antibacterial activity against Candida albicans, Escherichia coli and Staphylococcus aureu.