中文摘要：

针对木质素的转化，以木质素模型化合物愈创木酚催化加氢脱氧制备烷烃为模型反应，研究酸溶液中，活性炭负载Pd、Pt、Ru、Rh金属催化剂的催化性能。研究发现：在测试的催化剂中，Pd／C催化剂显示出较高催化加氢脱氧性能，烃类产物收率达到80％。随后，考查反应条件对催化性能的影响，发现在适中反应温度（200—250℃）、酸浓度（0．5wt％－1．0wt％）和较高氢气压力（5MPa）下，反应有利于烃类产物的生成。最后，探讨愈创木酚加氢脱氧的反应历程。

英文摘要：

As a model reaction for lignin transformation, the hydrodeoxygenation of guaiacol was studied over Car- bon supported Pd, Pt, Ru and Rh catalysts, and Pd/C was found effective for the formation of alkanes, the yield over 80%. Influences of reaction conditions on catalytic properties were investigated also and the results indicated that the proper reaction temperature （200-250℃）, concentration of acid （0. 5wt% -1.0wt% ） and high hydrogen pressure （5 MPa） are favorable to produce the alkanes. Finally, the mechanism of catalytic hydrodeoxygenation of guaiacol was proposed.