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Capability of cation exchange technology to remove proven N-nitrosodimethylamine precursors
  • ISSN号:1001-0742
  • 期刊名称:《环境科学学报:英文版》
  • 时间:0
  • 分类:TQ085.41[化学工程] TS411[农业科学—烟草工业;轻工技术与工程]
  • 作者机构:[1]State Key Joint Laboratory of Enuironmental Simulation and Pollution Control, School of Enuironment, Tsinghua Uniuersity, Belting 100084, China, [2]School of Chemical Engineering, China University of Petroleum (East China), qingdao 266580, China
  • 相关基金:supported by the National Natural Science Foundation of China (No.21477059); the National Water Major Project (No.2015ZX07402-002); the Fundamental Research Funds for the Central Universities (No.15CX02016A); the Tsinghua University Initiative Scientific Research Program (No.20131089247); the open project of State Key Joint Laboratory of environmental simulation and pollution control (Tsinghua University)
中文摘要:

N-nitrosodimethylamine (NDMA ) 先锋由一个断然控告的 dimethylamine 组和非极的一半组成,它鼓舞了我们开发一种指向的阳离子交换技术移开 NDMA 先锋。在这研究,我们测试了二位代表性的 NDMA 先锋, dimethylamine (直接存储器存取) 和 ranitidine (RNTD ) 的移动,由强壮的酸的阳离子交换树脂。结果证明 pH 极大地影响了交换效率,与高移动(直接存储器存取 ?>?78% 并且 RNTD ?>?94%) 在 pH 观察了 ?-1 当到先锋的交换能力的臼齿的比率是 4 时。交换顺序如下被获得:Ca 2?+?>?Mg2?+?>?RNTD+?>?K+?>?DMA+?>?NH4+?>?Na+ 。到 Na + 的直接存储器存取 + 的分区系数是 1.41 ? 敢椠 ?楤晳癡 吗?

英文摘要:

N-nitrosodimethylamine(NDMA) precursors consist of a positively charged dimethylamine group and a non-polar moiety, which inspired us to develop a targeted cation exchange technology to remove NDMA precursors. In this study, we tested the removal of two representative NDMA precursors, dimethylamine(DMA) and ranitidine(RNTD), by strong acidic cation exchange resin. The results showed that pH greatly affected the exchange efficiency, with high removal(DMA 〉 78% and RNTD 〉 94%) observed at pH 〈 pk_a-1 when the molar ratio of exchange capacity to precursor was 4. The exchange order was obtained as follows: Ca~(2+)〉 Mg~(2+)〉 RNTD~+〉 K~+〉 DMA~+〉 NH_4~+〉 Na~+. The partition coefficient of DMA~+to Na~+was 1.41 ± 0.26, while that of RNTD~+to Na~+was 12.1 ± 1.9. The pseudo second-order equation fitted the cation exchange kinetics well. Bivalent inorganic cations such as Ca~(2+)were found to have a notable effect on NA precursor removal in softening column test. Besides DMA and RNTD, cation exchange process also worked well for removing other 7 model NDMA precursors. Overall, NDMA precursor removal can be an added benefit of making use of cation exchange water softening processes.

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期刊信息
  • 《环境科学学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境科学研究中心
  • 主编:汤鸿霄
  • 地址:北京2871信箱双清路18号
  • 邮编:100085
  • 邮箱:jesc@263.net
  • 电话:010-62920553
  • 国际标准刊号:ISSN:1001-0742
  • 国内统一刊号:ISSN:11-2629/X
  • 邮发代号:2-580
  • 获奖情况:
  • 第三届中国出版政府奖
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  • 被引量:2348