设计合成了一种新型A-D-A含芴菲并咪唑和炔基基团的蓝光分子(FI),采用紫外吸收、光致发光光谱和循环伏安对材料进行了表征,发现该物质具有稳定的蓝光发射。采用旋涂的方法制备了非掺杂蓝光有机发光二极管,器件的最大电流效率为1.52 cd·A-1,最大功率效率为0.63 lm·W-1.
A novel A-D-A blue emitter containing fluorene, phenanthroimidazole and acetylene group moieties was synthesized and characterized, named as FI. Its photophysical and photochemical properties were systematically in-vestigated. The results showed FI exhibits excellent solubility, fluorescence, thermal stability and film formation, which is a good candidate for the fabrication of solution-processable organic light-emitting diodes. A non-doped blue organic light-emitting diode based on FI as the emitter showed the maximum luminance efficiency of 1. 52 cd·A-1 , and the maximum power efficiency could reach 0. 63 lm·W-1 .