中文摘要：

手性联萘酚高分子由单体（R）-3,3′-二炔基-6,6′-二正丁基-2,2′-联萘酚（R-M-1）和对苯二叠氮（M-1）通过CuAAC反应得到,通过1HNMR、13CNMR、FTIR、旋光度、GPC、热分析、荧光光谱等方法对单体和高分子进行了结构表征和性能测试。该高分子是通过＂Click＂反应得到的手性联萘酚高分子,本文探讨了手性高分子传感器对各种金属离子的荧光传感性质,结果表明,与其他离子如K＋、Mg2＋、Pb2＋、Co2＋、Ni2＋、Ag＋、Cd2＋、Cu2＋、Zn2＋等相比,Hg2＋几乎使高分子荧光完全淬灭。这表明,以三氮唑基团作为连接基团和识别位点的高分子可作为有效识别Hg2＋的荧光化学传感器。

英文摘要：

The optically active polybinaphthols incorporating triazole moiety in the polymer main chain could be obtained by the polymerization of（R）-6,6＇-dibutyl-3,3＇-diethynyl-2,2＇-binaphthol（R-M-1） and 1,4-diazidobenzene（M-1） via Click reaction.The responsive optical properties of the polymer on various metal ions were investigated by fluorescence spectra.The results indicate that this kind of triazole moiety as a receptor shows excellent fluorescence response on Hg2＋ detection without interference from other metal ions.