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Microwave hydrothermal synthesis and characterization of rare-earth stannate nanoparticles
  • 时间:0
  • 分类:TQ174.758[化学工程—陶瓷工业;化学工程—硅酸盐工业] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China, [2]Analytical and Testing Center, Jiangxi Normal University, Nanchang 330022, China
  • 相关基金:financially supported by the National Natural Science Foundation of China (Nos. 21641008 and 91622105); the Jiangxi Provincial Department of Science and Technology (Nos. 20161BAB203083 and 20151BDH80049)
中文摘要:

稀土元素的锡酸盐(行 2 Sn 2 O 7( 行 = Y, La-Lu )) 有 50 nm 的一条平均直径的 nanocrystals 通过灵巧的微波被准备在 200 点的热水的方法|

英文摘要:

Rare-earth stannate(Ln_2Sn_2O_7(Ln = Y, La–Lu)) nanocrystals with an average diameter of 50 nm were prepared through a facile microwave hydrothermal method at 200°C within 60 min. The products were well characterized. The effect of reaction parameters such as temperature, reaction time, p H value, and alkali source on the preparation was investigated. The results revealed that the p H value plays an important role in the formation process of gadolinium stannate(Gd_2Sn_2O_7) nanoparticles. By contrast, the alkali source had no effect on the phase composition or morphology of the final product. Uniform and sphere-like nanoparticles with an average size of approximately 50 nm were obtained at the p H value of 11.5. A possible formation mechanism was briefly proposed. Gd_2Sn_2O_7:Eu~(3+) nanoparticles displayed strong orange-red emission. Magnetic measurements revealed that Gd_2Sn_2O_7 nanoparticles were paramagnetic. The other rare-earth stannate Ln_2Sn_2O_7(Ln = Y, La–Lu) nanocrystals were prepared by similar approaches.

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