稀土元素的锡酸盐(行 2 Sn 2 O 7( 行 = Y, La-Lu )) 有 50 nm 的一条平均直径的 nanocrystals 通过灵巧的微波被准备在 200 点的热水的方法|
Rare-earth stannate(Ln_2Sn_2O_7(Ln = Y, La–Lu)) nanocrystals with an average diameter of 50 nm were prepared through a facile microwave hydrothermal method at 200°C within 60 min. The products were well characterized. The effect of reaction parameters such as temperature, reaction time, p H value, and alkali source on the preparation was investigated. The results revealed that the p H value plays an important role in the formation process of gadolinium stannate(Gd_2Sn_2O_7) nanoparticles. By contrast, the alkali source had no effect on the phase composition or morphology of the final product. Uniform and sphere-like nanoparticles with an average size of approximately 50 nm were obtained at the p H value of 11.5. A possible formation mechanism was briefly proposed. Gd_2Sn_2O_7:Eu~(3+) nanoparticles displayed strong orange-red emission. Magnetic measurements revealed that Gd_2Sn_2O_7 nanoparticles were paramagnetic. The other rare-earth stannate Ln_2Sn_2O_7(Ln = Y, La–Lu) nanocrystals were prepared by similar approaches.