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不同类型离子交换树脂对填充床电渗析中L-Lac~-和L-Glu~-分离的影响
  • ISSN号:1009-606X
  • 期刊名称:过程过程学报
  • 时间:2013.2.2
  • 页码:41-47
  • 分类:TS15[轻工技术与工程—纺织材料与纺织品设计;轻工技术与工程—纺织科学与工程]
  • 作者机构:[1]中国矿业大学北京化学与环境工程学院,北京100083, [2]中国科学院过程工程研究所,北京100190, [3]鞍山钢铁集团公司技术改造部,辽宁鞍山114021
  • 相关基金:国家自然科学基金资助项目(编号:21076214); 北京市自然科学基金资助项目(编号:5102030;8132047)
  • 相关项目:发酵液填充床电渗析中离子的迁移规律与选择性分离研究
中文摘要:

通过树脂静态吸附、常规电渗析及填充床电渗析的对比实验,考察了带有不同离子交换基团的树脂对发酵废液中L-Lac-和L-Glu-分离的影响.结果表明,碱性树脂201×7和WA30对2种组分的静态吸附量、L-Lac-/L-Glu-选择吸附比例均比酸性树脂001×1.1和WK10大.与常规电渗析相比,填充001×1.1(强酸型)、WK10(弱酸型)的填充床电渗析体系中L-Lac-和L-Glu-的跨膜迁移量及分离比例均有明显增加,填充001×1.1时分离比例最大可达22.22.填充201×7(强碱型)时两组分跨膜迁移量及分离比例均比常规电渗析小,最大分离比例分别为5.74和8.28.填充不同离子交换树脂体系的能耗对比表明,填充床淡室中填充树脂001×1.1和WK10时可促进L-Lac-和L-Glu-的迁移传递、提高二者的分离比例.

英文摘要:

The effect of ion exchange resins with different ionic groups on the separation of L-Lac- and L-Glu- from fermentation wastewater was investigated by resin static adsorption, conventional electrodialysis and packed-bed electrodialysis. The results of static adsorption showed that the selective adsorption ratio of L-Lac- and L-Glu- adsorbed by basic resins (201×7 and WA30) was higher than that adsorbed by acid resins (001 x 1.1 and WK10). Compared with conventional electrodialysis, the migration quantity and separation ratio of L-Lac- and L-Glu- in the dilute compartments filled with 001xl.1 (strong acid resin) and WK10 (weak acid resin) were obviously higher, the maximal separation ratio could reach 22.22 when the 001×1.1 resin was filled in the dilute compartment of electrodialysis. However, when the basic resins (201×7 and WA30) were filled in the dilute compartment, both migration quantity and separation ratio were lower than those of conventional electrodialysis, the maximal separation ratios of L-Lac- and L-Glu- in the concentrated compartments were 5.74 and 8.28 separately. The migration quantities and separation ratio of L-Lac- and L-Glu- and energy consumption in different electrodialysis systems showed that 001×1.1 and WK10 resins filled in the dilute compartments were beneficial to the separation of L-Lac- and L-Glu- in packed-bed electrodialysis.

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期刊信息
  • 《过程工程学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院过程工程研究所
  • 主编:张锁江
  • 地址:北京市海淀区中关村北二街1号过程大厦
  • 邮编:100190
  • 邮箱:CJPE@HOME.IPE.AC.CN GCGC@HOME.IPE.AC.CN
  • 电话:010-62554658
  • 国际标准刊号:ISSN:1009-606X
  • 国内统一刊号:ISSN:11-4541/TQ
  • 邮发代号:80-297
  • 获奖情况:
  • 国家中文核心期刊,中国科学院核心期刊,中国期刊方阵“双效”期刊,中国科学院优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:11515