以造纸废水二级生化出水为处理对象,利用硫铁矿催化H2O2降解废水中生物难降解有机物.在最佳工艺条件下:废水初始pH值为4、矿物投加量为1g·L-1、H2O2投加量为50mg·L-1、反应时间为1h,使废水的化学需氧量(COD)从初始136.0 mg·L-1降低到44.8 mg·L-1.结果表明:硫铁矿具有较高的催化活性,能提高H2O2的利用效率,并且可重复利用.
Effluent from secondary biological process for papermaking wastewater was employed as the model pollutants. Under the optimum conditions of the initial pH: 4, pyrite adding dosage: 1 g · L-1, H2O2 adding dosage: 50.0 mg· L-1, and the oxidation reaction time: 1 h, chemical oxygen demand (COD) of wastewater can decrease from 136.0mg· L-1 to 44.8 mg· L-1 The pyrite is found to be active to promote Fenton-like reaction with low cost due to high utilization efficiency of H2O2, furthermore, catalyst can be easily recovered from wastewater and reused.