以水杨醛肟为原料,经钠汞齐还原得到2-氨甲基-苯酚,再与水杨醛反应合成了配体L(L=bis(2-hydroxybenzyl)-amine).使用L配体和Co(NO3)·6H2O在水-甲醇溶液中制备了钠桥联的1维链状Co(Ⅱ)配合物[Na(methoxide)CoL2]n,解析了其晶体结构,应用元素分析、红外光谱等技术对配合物进行了表征.
2-(Aminomethyl)-phenol was synthesized using hydrochloridesalicylaldehyde oxime as raw material reduced by sodium amalgam.Then ligand L(L=bis(2-hydroxybenzyl)amine)was synthesized.A new complex[Na(methoxide)CoL2 ] n has been synthesized through the reaction of ligand L and Co(NO3)·6H2 O.The complex was characterized by X-ray diffraction,elemental analysis and IR.