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过渡金属催化碳氢键三氟甲基化
  • ISSN号：0567-7351
  • 期刊名称：《化学学报》
  • 时间：0
  • 分类：O622.2[理学—有机化学;理学—化学]
  • 作者机构：[1]北京分子科学国家实验室北京大学化学与分子工程学院生物有机与分子工程教育部重点实验室,北京100871, [2]中国科学院上海有机化学研究所金属有机化学国家重点实验室,上海200032
  • 相关基金：科技部973计划（No.2009CB825300）; 国家自然科学基金（Nos.20925207,21002001）资助
作者： 潘菲[1], 施章杰[1,2]
关键词： 过渡金属, 催化, 三氟甲基化, 碳氢键活化, 导向, 交叉偶联, transition metal, catalysis, trifluoromethylation, C—H activation, directing, cross-coupling
中文摘要：

近几年来,过渡金属催化的碳氢键活化的三氟甲基化反应取得了重要的进展.该领域的反应主要集中于端炔的sp碳氢键活化三氟甲基化反应、芳烃和杂环的sp2碳氢键活化的三氟甲基化反应以及烯丙基sp3碳氢键活化的三氟甲基化反应.本文简要介绍了该类反应的特点,概述了该领域的最新进展、面临的挑战及以后研究发展的重点和方向.

英文摘要：

In recent years,transition metal-catalyzed C—H trifluoromethylation has been well developed,which is mainly focused on the terminal alkyne C（sp）—H,aromatic and heterocyclic C（sp2）—H and allylic C（sp3）—H trifluoromethylation.This paper briefly overviews the latest developments in this field,the characteristics of various types of reaction,as well as the facing challenges and future direction.

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期刊信息
  • 《化学学报》
  • 北大核心期刊（2014版）
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编：周其林
  • 地址：上海市零陵路345号
  • 邮编：200032
  • 邮箱：hxxb@sioc.ac.cn
  • 电话：021-54925085
  • 国际标准刊号：ISSN：0567-7351
  • 国内统一刊号：ISSN：31-1320/O6
  • 邮发代号:4-209
  • 获奖情况:
  • 首届国家期刊奖,第二届国家期刊奖提名奖,中国期刊方阵“双高期刊”
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,英国英国皇家化学学会文摘,中国北大核心期刊（2000版）
  • 被引量:28694