溶剂诱导结晶(SINC)称为液体诱导结晶,它是结晶性高聚物在溶剂(或包括其蒸汽)作用下,在低于通常Tε下诱导结晶,而在高于通常Tε时能加速结晶的现象。本文主要对溶剂诱导结晶的机理、动力学和形态学进行了讨论。
The crystalline polymer could be crystallized below the glass transition temperature (Tε ), and accelerate crystallizing rate above Tε, when it was immersed in the solvent or solvent steam. This was called solventinduced crystallization, or liquid-induced crystallization. In this paper, the crystallization mechanism, kinetics and morphology of solvent-induced crystallization were reviewed and discussed.