中文摘要：

采用纤维素衍生碳、活性炭和介孔碳材料CMK-3为不同碳源前驱体,在不同磺酸化条件下制备磺酸化碳材料负载Ru的双功能催化剂,并用FTIR光谱、XRD、元素分析、热重分析、N2物理吸附-脱附进行了表征,考察了其对纤维素加氢反应的催化活性。结果表明：相比于纤维素衍生化碳,活性炭和介孔碳CMK-3为碳源经过磺酸化后制备的催化剂具有较强的结合—SO3H的能力和较高的催化活性,对多元醇具有良好的选择性,170℃下反应10 h六元醇的收率可高达84.0%。在循环使用时,磺酸化活性炭负载Ru催化剂催化活性有所降低,但可以保持对多元醇的选择性;而磺酸化介孔碳负载Ru催化剂存在少量S流失,转化率基本不变,但产物的选择性有所降低。

英文摘要：

Bifunctional catalysts of sulfonic acid carbon materials supported Ru were prepared,with different carbon source precursors,namely,cellulose derived carbon,actived carbon and mesoporous carbon materials CMK-3 under different sulfonic acid conditions.The structures of catalysts were characterized by FTIR spectrum,XRD,elemental analysis,thermogravimetric analysis and N2 physical adsorptiondesorption.The catalytic performance of hydrogenation reactions of cellulose were studied.Results show that,compared with cellulose derived carbon,activated carbon and mesoporous CMK-3 sulfonic acid carbon materials possess good combination ability with —SO3H,high catalytic activity and good polyols selectivity.Under 170 ℃ for 10 h,hexitols can yield up to 84.0%.When recycled,catalytic activity of activated carbon sulfonic acid materials supported Ru catalyst decreases,but keeps on selectivity of polyols; mesoporous carbon sulfonic acid materials supported Ru catalyst has problems with the loss of S,and conversion rate remaines about the same,but the product selectivity is reduced.