中文摘要：

为改善p环糊精的水溶性，将β-环糊精和甘氨酸在碱性条件下用环氧氯丙烷连接起来，得到水溶性极好的甘氨酸-β-环糊精，研究了甘氨酸-β-环糊精对菲的增溶、解吸行为，考察了pH、甘氨酸-β环糊精初始浓度、温度、不同环糊精类型对菲解吸的影响。结果表明，甘氨酸-β-环糊精对菲的增溶效果显著，其初始质量浓度为30g／L时，对菲的增溶倍数可以达到近30倍；甘氨酸-β-环糊精对菲的解吸随pH的升高而降低；升高甘氨酸-β-环糊精初始浓度和温度有利于菲的解吸；甘氨酸口环糊精对菲的解吸好于α-环糊精和β-环糊精，甘氨酸-β-环糊精对菲污染土壤的解吸符合准二级动力学方程。该静态解吸研究可以为菲污染土壤的修复提供基础信息。

英文摘要：

High water soluble glycine-β-cyclodextrin was synthesized by β-cyclodextrin and glycine under basic condition with epichlorohydrin used as the cross-linking agent. The effects of obtained glycine-β-cyclodextrin on en- hanced solubilization and desroption behavior of phenanthrene in soil was studied, and the influence factors of phenan- threne desorption, such as p H, initial concentration of glycine-β-cyclodextrin, temperature and CD type, were also in- vestigated and described in details. The IR spectra of glycine-β-cyclodextrin showed that the added hydrophilic groups such as arnide and carboxy improved the poor solubility of β-cyclodextrin, and inner hydrophobic structure of β-cyclo- dextrin could accelerate the solution of hydrophobic organic matters. The obtained glycine--β--cyclodextrin presented perfect capacity of phenanthrene solubilization, 30 g/L of glycine-β-cyclodextrin could increase the solubility of phe- nanthrene by about 30 times. A higher pH resulted in a lower efficiency of phenanthrene desorption in soil, and the phe- nanthrene desorption efficiency increased with increasing temperature and initial glycine-β-cyclodextrin concentration. The data of phenanthrene desorption in soil were well fitted by the pseudo second-order rate equation. This static desorption research provided some fundamental information for the remediation of phenanthrene-contarfiinated soil.