质子交换膜作为燃料电池和液流电池的关键材料之一,近二十年来得到世界各国科学家的广泛关注和深入研究,先后研究开发出含氟高分子类、碳氢聚合物类、芳香烃聚合物类,以及有机/无机杂化材料的质子交换膜.在总结归纳这一领域的研究成果基础上,结合本课题组在液流电池领域的质子交换膜研究进展,论述质子交换膜技术在新能源技术领域未来若干年的研究开发重大需求,展望质子交换膜材料设计与可能的绿色合成技术路线.
Proton exchange membranes regarded as a key materials in the processes of developing fuel cell and flow battery have obtained widely attention and extensive study during last two decades, many sorts of mem- branes were proposed in the world, such as fluorinated polymer, aromatic backbone and organic/inorganic hybrid membranes. Based on the review of the R & D activity and achievements in this field, as well the research results of proton conductive membrane for flow battery in our group, this paper clarifies the potential demand of proton exchange membrane in the renewable energy market in the future, and gives a perspective in developing proton exchange membranes with environmental friendly approaches.