中文摘要：

探究了针铁矿催化转化溴酚（2，4-DBP或2，4，6-TBP）生成羟基化多溴联苯醚（HO-PBDEs）和溴代二噁英（ PBDD／Fs）的可能性．结果表明，针铁矿可以在常温和干反应条件下有效地催化转化溴酚化合物生成HO-PBDEs和PBDD／Fs．反应16 d，97．3％的2，4-DBP被针铁矿氧化转化，其中2．4％被转化为2′-OH-BDE-68，2．8％被转化为2，2′-OH-BB-80，0．2％被转化1，3，8-TrBDD，0．4％被转化为2，4，6，8-TeBDF．同样的反应时间内，98．7％的2，4，6-TBP被针铁矿氧化转化，反应产物可能为2′-OH-BDE-121、4′-OH-BDE-121、1，3，6，8-TeBDD和1，3，7，9-TeBDD．根据检测到的产物，提出了针铁矿氧化转化溴酚的可能途径．

英文摘要：

The formation of hydroxylated polybrominated diphenyl ethers （ HO-PBDEs ） and brominated dibenzo-p-dioxins, dibenzofurans （ PBDD/Fs ） from goethite-catalyzed oxidation of bromophenols （ BPs, e. g., 2, 4-DBP and 2, 4, 6-TBP ） was investigated. Results showed that goethite readily catalyzed the conversion of 2,4-DBP and 2,4,6-TBP to HO-PBDEs and PBDD/Fs under dry conditions and at ambient temperature. In 16 d, 97.3%of 2,4-DBP was converted and the yields of 2′-OH-BDE-68, 2,2′-OH-BB-80, 1,3,8-TrBDD and 2,4,6,8-TeBDF were 2.4%, 2.8%, 0.2% and 0. 4%, respectively. Similarly, 98. 7% of 2,4,6-TBP was transformed and the possible reaction products were 2′-OH-BDE-121, 4′-OH-BDE-121, 1,3,6,8-TBDD and 1,3,7,9-TBDD. The possible formation pathways for the goethite-catalyzed oxidation of bromophenols were proposed.