采用低温固硫熔炼新工艺对辉锑矿一步熔炼进行研究。结果表明:在液固比为5(质量比)、聊(Na2C03)/m(KCl)为4(质量比)、粉煤质量过量系数为2倍、ZnO质量过量系数为1.2倍、熔炼温度为850℃、熔炼时间为2h的最优条件下,sb的直收率为90%(质量分数),粗锑品位为92%(质量分数),辉锑矿中的硫以ZnS的形态固定于渣中,渣中硫固定量为84%(质量分数)。较传统冶火法炼锑工艺,熔炼温度降低350℃以上,降低了能耗,解决了辉锑矿熔炼过程中低浓度S02污染的问题。
A low-temperature and sulfur-fixing smelting process was applied to separate antimony from stibnite. The results show that the direct recovery rate of Sb is 90%(mass fraction), and the grade of Sb is 92%(mass fraction), and the sulfur fixing in solid slag is 84% (mass fraction) as ZnS under the following optimum conditions: liquid-solid ratio 5 (mass ratio), m(Na2CO3)/m(KC1) for 4 (mass ratio), quality excessive coefficient of pulverized coal for 2 times, quality excessive coefficient of ZnO for 1.2 times, smelting temperature for 850 ℃, smelting time for 2 h. Compared with the traditional methods of pyrometallurgy of antimony, this process can not only lower smelting temperature more than 350 ℃ and save energy consumption significantly, but also considerably reduce the atmospheric emissions of low-concentration sulfur dioxide.