为利用高韧性β-PP制备高性能碳酸钙填充PP复合材料,该文采用负载β-成核剂的纳米碳酸钙(β-CC)、纳米碳酸钙(CC)和微米碳酸钙(WC)填充PP制备β-PP复合材料。结晶行为与熔融特性的DSC结果表明,加入CC和WC提高PP结晶温度,β-CC 填充PP复合材料的结晶温度高于CC和WC填充PP,表明β-CC对PP结晶的异相成核作用高于CC和WC。XRD结果表明,CC和WC填充PP复合材料主要形成α-晶,β-CC 填充PP复合材料主要形成β-晶。采用β-CC可制备高β-晶含量的碳酸钙填充PP复合材料。
In order to obtain high performance PP composites using high toughnessβ-PP,theβ-PP com-posites were prepared by PP filled nano-CaCO3 (CC)supported β-nucleating agent (β-CC),CC and micro-CaCO3 (MC ). The result of differential scanning calorimetry indicated that the crystallization peak temperatures of PP increased by adding MC,the crystallization peak temperatures ofβ-CC filled PP composites were higher than those of composites filled by MC and CC,and the heterogeneous nucleation ofβ-CC was higher than those of MC and CC for iPP crystallization.The results on wide-angle X-ray dif-fraction analysis demonstrated that the MC and CC filled iPP composites mainly formedα-crystal,and theβ-CC filled composites mainly formed β-crystal.The β-iPP composites with high filler could be prepared by adding β-CC into iPP matrix.