采用蓝色磷光染料bis [ (4,6-diflourophenyl)-pyridinato-N, C2 ' ) ] (picolinato) Iridium (III) (FIrpic)和黄色磷光染料bis[ 2- (4-tertbutylphenyl) benzothiazolato-N, C2, ] iridium (acetylacetonate) [ (t-bt) 2 Ir (acac) ] 为超薄层,制备了结构为ITO/NPB/mCP/(t-bt) 2 Ir (acac)/mCP/Flrpic/mCP/TPBi/Mg : Ag的白色有机电致发光器件。通过调节磷光染料双超薄层Hrpic和(t-bt)。Ir(acac)的厚度,优化了白光器件的性能。结果表明,白光器件的最高电流效率为13.08cd/A,最高功率效率为7.21 1m/W,发光光谱稳定,在9V时得到色坐标为(0.33,0.33)的标准白光,并且在较宽的电压范围内仅有(±0.08,±0.08)变化。这是由于超薄层Flrpic和(t-bt)。Ir(acac)形成的陷阱效应直接俘获电子和空穴,从而将载流子复合区域限制在一定范围内,不仅有利于增加激子的辐射发光效率,且提高了光谱的稳定性。
The white organic light-emitting devices (OLEDs) with a structure of ITO/NPB/mCP/(t-bt)2Ir (acac)/mCP/FIrpic/mCP/TPBi/Mg : Ag were fabricated using a blue and yellow phosphorescent dyes of bis[(4,6- diflourophenyl)-pyridinato-N,C2')](picolinato) Iridium(III) (FIrpic) and bis[2-(4-tertbutylphenyl)benzothiazola- to-N, C2, ]iridium (acetylacetonate) [ (t-bt) 2 Ir (acac) ] as ultrathin layers, respectively. The performance of white OLEDs has been optimized by adjusting the film thickness of (t-bt)2Ir(acac) and Firpic. The results showed that a pure white organic light-emission was obtained with a current efficiency of 13.08 cd/A and a power efficiency of 7.21 lm/W. The CIE (Commissions Internationale De L'Eclairage) coordinates near (0.33,0.33) was observed at 9 V with a slight variation of (±0.08, ±0.08) in a wide range of voltages. The high power efficiency and stable electroluminescence were attributed to the confining emission zone function of direct carrier trapping in the ultrathin layers.