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煤油共生矿区含油煤层自燃特性试验研究
  • ISSN号:1003-3033
  • 期刊名称:《中国安全科学学报》
  • 时间:0
  • 分类:X936[环境科学与工程—安全科学]
  • 作者机构:[1]河南理工大学安全科学与工程学院,河南焦作454003
  • 相关基金:国家自然科学基金资助(U1361205,51304071,51304073); 河南理工大学博士基金资助(B2012-068,B2012-085)
中文摘要:

为研究煤油共生矿区煤自燃特性,利用煤氧化动力学测定系统,测试原煤样与含油煤样。根据煤自燃倾向性判定标准、耗氧速率及煤氧复合反应理论,分析试验结果。以铜川下石节煤矿煤样和原油样品(煤岩渗出的油,文中称为原油)为例,向原煤样中添加一定量的原油制备含油煤样,通过试验获得原煤样与含油煤样低温阶段(30--240℃)的自燃特性参数。研究结果表明,2种煤样自燃倾向性等级均为自燃,但原煤样更接近于易自燃;相同温度条件下含油煤样的耗氧速率、CO与CO2的生成量均比原煤样小;在低温氧化阶段,造成上述结果的主要原因是,原油充填了煤样的部分空隙和孔隙,阻碍了煤氧复合反应。

英文摘要:

In order to study the spontaneous combustion of coal in coal-oil coexistence area, original coal samples and coal samples added with oil were tested by using of a coal oxidation kinetics testing method system. The test results were analyzed based on the spontaneous combustion tendency identification stand- ard, oxygen consumption rates and reaction of coal oxidation theory. The coal samples were collected from Tongchuan Xiashijie coal mine and the oil was also collected from the same coal mine. The spontaneous combustion characteristic parameters of both coal samples at low temperature (30 - 240 ~C ) were tested by using the test system. The results show that spontaneous combustion tendency of coal samples belongs to spontaneous combustion while original coal sample tends to easy spontaneous. Simultaneously, the oxygen consumption rates and the generation column (include CO and CO2 ) of coal sample containing oil are smaller than original coal sample at the same temperature. In addition, the reason of these results is that oil filling in part of coal sample porosity and pore obstructs the reaction of coal and oxidation.

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期刊信息
  • 《中国安全科学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国职业安全健康协会
  • 主编:徐德蜀
  • 地址:北京市东城区和平里九区甲4号安信大厦A306室
  • 邮编:100013
  • 邮箱:csstlp@263.net
  • 电话:010-64464782
  • 国际标准刊号:ISSN:1003-3033
  • 国内统一刊号:ISSN:11-2865/X
  • 邮发代号:
  • 获奖情况:
  • 中国科技论文统计用刊,第一届中国科协期刊优秀学术论文奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),波兰哥白尼索引,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:31001