中文摘要：

采用化学还原法,在具有不同微观结构的规整的不锈钢网和聚纤维素酯薄膜表面合成了银纳米颗粒。利用氟化试剂对复合界面进行处理,形成超疏水性能的界面,能有效地浓缩目标分子。以罗丹明6G（R 6G）为分析物,纳米银修饰聚纤维素酯薄膜为基底,采用表面增强拉曼散射（SERS）分析了氟化处理前后基底对目标分子的检测能力。实验结果表明,具有超疏水性能的复合基底对R 6G分子的检出限为1×10~（-16）mol/L。以纳米银修饰的不锈钢网和聚纤维素酯两种复合材料为基底,对常用杀虫剂敌百虫的检出限分别为1×10~（-15）mol/L和1×10~（-16）mol/L。

英文摘要：

Super hydrophobic interface modified with silver nanoparticles was fabricated for the detection of pesticide residues.By using a chemical reduction method,silver nanoparticles were deposited on the substrate surfaces with different microscopic pore structures.Two kinds of composite substrates,including regular stainless steel mesh and cellulose polyester film,were used.The pre-treatment of the substrate with fluoridated reagents was used to form a super hydrophobic interface,which made the target molecules on the surface concentrate effectively.The surface with the cellulose polyester substrate was used to detect Rhodamine 6G（R 6G） effectively with surface enhanced Raman scattering（SERS） technique.The results showed that the detection limit was 10~（-16）mol/L.In addition,the surfaces based on the stainless steel mesh and cellulose polyester substrate were used to detect trichlorfon pesticide with detection limits of 1×10~（-15）mol/L and 1×10~（-16）mol/L,respectively.