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中文摘要：
配合物1由醋酸镉和Nahca（对羟基肉桂酸钠）在水溶液中反应得到,配合物2由醋酸铜,Hhca和phen在水和乙醇混合溶液中反应得到。配合物1属正交晶系,Pbcn空间群。配合物2属单斜晶系,C2/c空间群。配合物1和2中配体中的羧酸根与金属离子都是螯合配位的,末端羟基没有参与配位。配合物1和2的结构中都包含了丰富的氢键。通过氢键作用,配合物1形成了三维网状超分子结构,配合物2形成了二维层状超分子结构。
英文摘要：
Complex 1 [Cd（hca）2（H2O）3] was obtained by the reaction of CdCl2·2H2O,NaOH and 4-hydroxycinnamic acid（Hhca） and complex 2 [Cu（hca）2（phen）] was obtained by the reaction of Cu（Ac）2·H2O,4-hydroxycinnamic acid and 1,10-phenanthroline.The crystal structure reveals that complex 1 is of orthorhombic,space group Pbcn with a=2.629 7（4） nm,b=1.095 76（17） nm,c=0.732 16（11） nm,V=2.109 7（6） nm^3,Z=4,μ=1.092 mm-1,Dc=1.665 Mg·m-3,F（000）=1 072 and the complex 2 is of monoclinic,space group C2/c with a=2.420 5（5） nm,b=1.006 1（2） nm,c=0.732 2（11） nm,β=109.55°,V=2.530 8（9） nm^3,Z=4,μ=0.912 mm^-1,Dc=1.496 Mg·m^-3,F（000）=1 172.Both com-plexes are mononuclear but hydrogen bonds enrich the structural construction.By the linkage of hydrogen bonds,complex 1 shows a 3D supramolecular network and complex 2 shows a 2D supramolecular network.
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