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不同原料堆肥胡敏酸的荧光特性
  • ISSN号:1001-6929
  • 期刊名称:《环境科学研究》
  • 时间:0
  • 分类:X705[环境科学与工程—环境工程]
  • 作者机构:[1]中国环境科学研究院水环境系统工程研究室,北京100012, [2]东北农业大学生命科学学院,黑龙江哈尔滨150030, [3]黑龙江省环境工程评估中心,黑龙江哈尔滨150076, [4]北京师范大学环境学院,北京100875
  • 相关基金:国家自然科学基金项目(51078340);国家“十一五”科技支撑计划项目(2006BAC06B04,2008BADC4B00,2009BADC2B04);农业科技成果转化资金项目(2008GB24420470)
中文摘要:

从以植物、鸡粪、生活垃圾、污泥、牛粪和杂草为主要原料的6种堆肥产品和草炭中提取胡敏酸类物质,对他们的激发、发射、同步和三维荧光光谱进行了研究.结果表明:各荧光谱图中,草炭胡敏酸特征荧光峰出现在最大波长处,植物、牛粪和生活垃圾堆肥胡敏酸次之,鸡粪和杂草堆肥胡敏酸紧接其后,污泥堆肥胡敏酸最低,并且含有较强的类蛋白荧光.各类堆肥的类富里酸荧光峰强度与类胡敏酸荧光峰强度的比值从小到大及腐殖质化程度由高到低均依次为0.708(草炭堆肥),0.893(植物堆肥),0.932(牛粪堆肥),0.940(生活垃圾堆肥),1.155(杂草堆肥),1.206(鸡粪堆肥)和1.521(污泥堆肥).相对于草炭胡敏酸,堆肥胡敏酸普遍分子结构简单、芳构化程度较低,且具有较强的土壤元素活化能力,并且植物、牛粪和生活垃圾堆肥的胡敏酸在增大土壤环境容量及降低污染土壤中重金属移动性方面效果最佳.

英文摘要:

Humic acids(HA) extracted from grass peat and six types of composts based on plants, fowl manure, domestic waste, sludge, dairy manure and weeds as the raw materials were studied. The fluorescence emission spectra, excitation spectra, synchronous fluorescence and three-dimensional excitation emission matrix fluorescence of the humic acids were investigated. Of all the fluorescence results, HA from grass peat had characteristic peaks of longest wavelength followed by HA from compost based on plants, dairy manure, domestic waste, fowl manure, weeds and sludge, in decreasing order. In addition, HA from composts based on sludge had high strength peaks, imlicating the existence of proteins. The samples had obviously different ratios of the strength of the fulvic-like peak to the humic-tikc peak, with values of 0. 708 ( grass peat) , 0. 893 ( compost based on plants) , 0. 932 (compost based on dairy manure), 0. 940 (compost based on domestic waste), 1. 155 (compost based on weeds), 1. 206 (compost based on fowl manure) and 1.521 (compost based on sludge ). The molecular structure of HA from the composts was not complicated and of low aromatization relative to that from grass peat. The HA from these composts had soil activation ability. HA from the composts based on the plants, dairy manure and domestic waste can increase the soil environment capacity and efficiently reduce the mobility of heavy metals in the polluted soil.

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期刊信息
  • 《环境科学研究》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国环境保护部
  • 主办单位:中国环境科学研究院
  • 主编:刘鸿亮
  • 地址:北京安外大羊坊8号中国环科院内
  • 邮编:100012
  • 邮箱:hjkxyj@163.com
  • 电话:010-84915128
  • 国际标准刊号:ISSN:1001-6929
  • 国内统一刊号:ISSN:11-1827/X
  • 邮发代号:82-384
  • 获奖情况:
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国国家哲学社会科学学术期刊数据库,中国北大核心期刊(2000版)
  • 被引量:33433