欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
以Ni/CMK-3为催化剂，采用BET比表面积、X射线衍射和氢气程序升温还原对催化剂进行了表征.考察了不同Ni负载量、反应温度、反应初始压力及反应时间条件下，甲醇水相重整制氢与邻甲酚原位加氢的耦合反应.结果表明，当Ni负载量为20%、反应温度为230℃、反应前冷压为0.1 MPa、水-甲醇-模型化合物摩尔比为50颐15颐1及反应9 h时，邻甲酚转化率最高为45.4%.分别对比了甲醇、甲酸、甘油和异丙醇作为供氢溶剂对原位加氢反应的影响，其中以甲酸为供氢溶剂时，邻甲酚的转化率最高达82.2%.对比了甲酚3种同分异构体原位加氢的效果，发现邻甲酚和间甲酚的反应效果相差不大，而对甲酚的转化率则远低于邻甲酚和间甲酚.对20%Ni/CMK-3在原位加氢实验中的使用寿命进行了考察.
英文摘要：
In situ hydrogenation was studied by means of Ni loading, temperature, initial pressure, and reac-tion time over Ni/CMK-3 catalysts. The catalysts were characterized by X-ray diffraction（ XRD） , H2 tempera-ture programmed reduction（ H2-TPR） and N2 adsorption-desorption isotherms. The results revealed that the optimal conditions were confirmed as follow： Ni loading of 20%（ mass fraction ） , reaction temperature of 230 ℃, initial pressure of 0. 1 MPa, reaction time of 9 h for in situ hydrogenation. The maximum conversion of o-cresol in optimal condition was determined as 47. 56%. Compared with the effect of hydrogen donor solvents, formic acid was the best of four kinds of solvents. The comparsion of cresol isomers, recyclability of Ni/CMK-3 were also discussed.
同期刊论文项目
同项目期刊论文
High yield of renewable hexanes by direct hydrolysis–hydrodeoxygenation of cellulose in an aqueous p
Hydrogen from biomass degradation production by aqueous-phase reforming: An overview on the catalyst
Investigation on the Aqueous-phase Hydrogenation of Bio-oil for Saturated Alcohols Production over N
Preliminary investigation on hydrogen-rich gas production by co-steam-reforming of biomass and crude
Different Methods for Evaluating Pinewood Sawdust Pyrolysis Kinetics by Thermogravimetry Mass Spectr
Synthesis of Fe3O4-nanocatalysts with different morphologies and its promotion on shifting C5 + hydr
Influence of manganese promoter on co-precipitated Fe-Cu based catalysts for higher alcohols synthes
Ultrasonic-assisted production of biodiesel from transesterification of palm oil over ostrich eggshe
Preparation and characterization of carbonaceous adsorbents from sewage sludge using a pilot-scale m
Study of thermal decomposition and kinetics of biomass/Swill-cooked dirty oil blends during co-pyrol
Production of light olefins from biosyngas by two-stage catalytic conversion process via dimethyl et
Decentralized Heating in a Rural Village using Biomass Gasification and Anaerobic Digestion: Economi
Analysis of product distribution and characteristics in hydrothermal liquefaction of barley straw in
Molecular Dynamics Simulations of Interaction between the Mixture of Glycerol and 1,6-hexanediol and
Hydrogen from biomass degradation production by aqueous-phase reforming : An overview on the catalys
Influence of alkali catalyst on product yield and properties via hydrothermal liquefaction of barley
Chuangzhi Wu,Influence of manganese promoter on co-precipitated Fe-Cu based catalysts for higher alc
期刊信息
位置：