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不同温度下尼龙6性能和结构变化的原位研究
  • ISSN号:1000-3304
  • 期刊名称:《高分子学报》
  • 时间:0
  • 分类:TQ323.6[化学工程—合成树脂塑料工业]
  • 作者机构:[1]天津大学材料学院,天津300072, [2]山东商务职业学院,烟台264670
  • 相关基金:国家自然科学基金(基金号51173130)资助项目
中文摘要:

利用拉伸热台对尼龙6在不同温度下的拉伸性能进行了测试和分析.随着拉伸温度的升高,尼龙6样品的屈服强度和杨氏模量逐渐下降.采用了一个阿伦尼乌斯模型来描述尼龙6屈服强度与拉伸温度之间的关系,并描述了尼龙6样品黏度、玻璃化温度对屈服强度的影响.通过原位同步辐射广角衍射分析,我们发现未拉伸的尼龙6样品中的α相与γ相的相对比率随温度升高而下降.在拉伸条件下,随着拉伸温度的升高,样品的结晶部分容易产生滑移或晶区的熔融,有序程度下降,因而样品承载外力的能力下降,体现为屈服强度和杨氏模量的下降.

英文摘要:

The temperature dependent stress-strain curves of Nylon 6 were obtained via tensile hot stage,and the in situ WAXS experiments were measured simultaneously. The results indicated that the temperature related yield stress,breaking strength and modulus of Nylon 6 can be described by the Arrhenius equation. During the process of stretching Nylon 6 experienced elastic deformation,yield, strain hardening and fracture. The yielding on Nylon 6 stress-strain curves was unobvious with the low draw rate, meanwhile, the yielding turned to more unobvious gradually at higher stretching temperatures. The stress-strain curves of Nylon 6 are similar to each other within the measured temperature range. Nevertheless, the yield strength and modulus decreased with the increasing of stretching temperature. By analyzing the WAXS profile,it was found that the a-phase: T-phase ratio of undeformed Nylon 6 samples decreased along with the temperature increased. Also, at high temperatures, the crystalline phase of Nylon 6 slipped and/or melted during tensile deformation more easily. In the meantime, the relationship between the stretching temperature and mechanical properties was obtained after fitting the temperature dependent results. It was found that the temperature related relationship obeys the Arrhenius equation. In addition,the viscosity dependence of yield stress was given in the paper.

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174