中文摘要：

采用Adler-Longo法,设计合成了两种系列共8种具有对称结构的中位四取代酯类卟啉化合物,通过~1H NMR,~（13）C NMR,IR对其分子结构进行了表征,通过紫外-可见光谱法（UV）、荧光光谱法（PL）和循环伏安法（CV）对这些化合物的光电性能进行了研究;结果表明,所合成的中位四取代酯类卟啉化合物结构正确,并均具有较高的荧光量子效率、较低的轨道能隙,是一类较好的光致电材料,在有机半导体材料、有机太阳能电池等方面具有潜在的应用前景。

英文摘要：

Using the Adler-Longo method,the two series of the 8 kinds of a median tetra-substituted ester por-phyrin compounds which has the symmetrical structure have been designed and synthesized in this paper,and their structure was characterized by1 H NMR,13 C NMR,IR.Their optoelectronic properties were studied by UV-Vis absoption spectra and Fluorescence emission spectra,and its orbital energy level was studied by the cy-clic voltammetry.Results indicate that the synthesis of the median tetra-substituted ester porphyrin compounds have a high quantum efficiency and a lower orbital energy gap.In addition,they are preferable light calling ma-terial and have broad application prospects in the organic semiconductor material,organic solar cells,etc.