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Atmospheric-Pressure DBD Cold Plasma for Preparation of High Active Au/P25 Catalysts for Low-Temperature CO Oxidation*
  • ISSN号:1009-0630
  • 期刊名称:《等离子体科学与技术:英文版》
  • 时间:0
  • 分类:TQ426.6[化学工程] O613.71[理学—无机化学;理学—化学]
  • 作者机构:[1]College of Physical Science and Technology, Dalian University, Dalian 116622, China, [2]Key Laboratory for Non-traditional & Functional Materials Preparation of EducationDepartment of Liaoning Province, Dalian University, Dalian 116622, China
  • 相关基金:supported by National Natural Science Foundation of China (Nos. 11505019, 21173028), the Science and Technology Research Project of Lianing Provincial Education Department (No. L2013464), the Scientific Research Foundation for the Doctor of Liaoning Province (No. 20131004), and the Dalian Jinzhou New District Science and Technology Plan Project (No. KJCX-ZTPY-2014-0001)
中文摘要:

Cold plasma generated by dielectric barrier discharge(DBD) at atmospheric pressure was adopted for preparation of commercial TiO2 Degussa P25 supported Au catalysts(Au/P25-P) with the assistance of the deposition-precipitation procedure.The influences of the plasma reduction time and calcination on the performance of the Au/P25-P catalysts were investigated.CO oxidation was performed to investigate the catalytic activity of the Au/P25 catalysts.The results show that DBD cold plasma for the fabrication of Au/P25-P catalysts is a fast process,and Au/P25-P(4 min) exhibited the highest CO oxidation activity due to the complete reduction of Au compounds and less consumption of oxygen vacancies.In order to form more oxygen vacancies active species,Au/P25-P was calcined to obtain Au/P25-PC catalysts.Interestingly,Au/P25-PC exhibited the highest activity for CO oxidation among the Au/P25 samples.The results of transmission electron microscopy(TEM) indicated that the smaller size and high distribution of Au nanoparticles are the mean reasons for a high performance of Au/P25-PC.Atmosphericpressure DBD cold plasma was proved to be of great efficiency in preparing high performance supported Au catalysts.

英文摘要:

Cold plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure was adopted for preparation of commercial TiO2 Degussa P25 supported Au catalysts (Au/P25- P) with the assistance of the deposition-precipitation procedure. The influences of the plasma reduction time and calcination on the performance of the Au/P25-P catalysts were investigated. CO oxidation was performed to investigate the catalytic activity of the Au/P25 catalysts. The results show that DBD cold plasma for the fabrication of Au/P25-P catalysts is a fast process, and Au/P25-P (4 min) exhibited the highest CO oxidation activity due to the complete reduction of Au compounds and less consumption of oxygen vacancies. In order to form more oxygen vacancies active species, Au/P25-P was calcined to obtain Au/P25-PC catalysts. Interestingly, Au/P25- PC exhibited the highest activity for CO oxidation among the Au/P25 samples. The results of transmission electron microscopy (TEM) indicated that the smaller size and high distribution of Au nanoparticles are the mean reasons for a high performance of Au/P25-PC. Atmospheric- pressure DBD cold plasma was proved to be of great efficiency in preparing high performance supported Au catalysts.

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期刊信息
  • 《等离子体科学与技术:英文版》
  • 主管单位:中国科学院 中国科协
  • 主办单位:中国科学院等离子体物理研究所 中国力学学会
  • 主编:万元熙、谢纪康
  • 地址:合肥市1126信箱
  • 邮编:230031
  • 邮箱:pst@ipp.ac.cn
  • 电话:0551-5591617 5591388
  • 国际标准刊号:ISSN:1009-0630
  • 国内统一刊号:ISSN:34-1187/TL
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),英国科学文摘数据库
  • 被引量:89