欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
从易得原料D-苯甘氨酸出发,经酯化、N-烷基化及还原等三步反应合成了五个手性β-氨基醇5和6.以此为手性配体,对催化芳香醛的不对称烯丙基化反应进行了初步研究,显示了中等程度的立体选择性.
英文摘要：
Chiral β-amino alcohols 5 and 6 were prepared efficiently from D-phenylglycine through esterification,N-alkylation and reduction reactions.By using these compounds as the chiral ligand,preliminary study on asymmetric allylation reactions of aromatic aldehyde was carried out,in which the moderate enantioselectivities were achieved.
同期刊论文项目
同项目期刊论文
Synthesis of Bicyclic Pyridones via Cyclocondensation of Heterocyclic Ketene Aminals with beta-Ketoe
Artemether/hydroxypropyl-beta-cyclodextrin host-guest system: Characterization, phase-solubility and
A Facile Route to 1,3-Diazaheterocycle-Fused [1,2-a]Indole Derivatives via Acetic Acid Catalyzed Cyc
An efficient one-pot synthesis of heterocycle-fused 1,2,3-triazole derivatives as anti-cancer agents
Facile Route to 1,3-Diazaheterocycle-Fused [1,2b]Isoquinolin-1(2H)-one Derivatives via Substitution-
One-Pot Synthesis of Pyrimidines via Cyclocondensation of b-Bromovinyl Aldehydes with Amidine Hydroc
Host-Guest System of Nimbin and beta-Cyclodextrin or Its Derivatives: Preparation, Characterization,
期刊信息
位置：