中文摘要：

以n-BuLi／Cy2NCu为引发剂，在-15℃的四氢呋喃中，实现了极性单体甲基丙烯酸缩水甘油酯（GMA）的阴离子聚合，并研究了它与甲基丙烯酸甲酯（MMA）的共聚。结果表明，在c（n-Bu（Cy2N）CuLi）为0．158mol／L、cGMA为0．378mol／L时，GMA的转化率达94．6％，Mn^-为5609，Mw^-／Mn^-为1．46。此外，该催化剂可使GMA和MMA发生共聚反应，其中GMA的聚合活性大于MMA的聚合活性。

英文摘要：

Anionic polymerization of glycidyl methacrylate （GMA） has been carried out with n-BuLi/CyzN Cu as initiator in THF below - 15 ℃. Its copolymerization with methyl methacrylate （MMA） was also studied. It is demonstrated that the percentage of conversing monomer could reach to 94.6 %, and Mw^-/Mn^- is 1.46 when c （n-BuCy2NCuLi） is 0. 158 mol/L and CGMA is 0. 378 mol/L. Furthermore, the copolyers of GMA and MMA was resulted by the catalysts and the results showed that GMA was more easily polymerized than MMA in this polymerization system.