为进一步提高Er^3+1.53μm波段的光谱特性,在Er^3+^4I11/2→4I/13/2和Ce3+:2F5/2→F7/2跃迁间存在能量失配(1400cm。附近)的Er^3+/Ce^3+共掺碲酸盐(TeO2-Bi203-TiO2)玻璃中引入了高声子能量SiO2组分。测试分析了不同Si02组分含量下的Er^3+吸收光谱、上转换发光谱、1.53btm波段荧光谱、荧光寿命、放大品质因子和玻璃样品的热性能。结果表明:由于增强的Er^3+/Cd^3+离子间能量传递,当玻璃样品中SiO2含量达到9%(摩尔分数)时,Er^3+的1.53μm波段荧光强度得到显著提高。同时,荧光半高宽随SiO2组分含量相应展宽,而玻璃热稳定性随之提高。
In order to further improve the 1.53/zm band spectroscopic properties of Era+ , a high phonon-energy oxide of SiOz was introduced into the Era+/Ce3+ co-doped tellurite glass (TeOz--Biz O3--TiOz ) with the energy mismatch (--1 400 cm-1 ) between the Er3+4I11/2→4I/13/2和Ce3+:2F5/2→F7/2 transitions. The absorption spectra, up-conversion emission spectra, 1.53μm band fluorescence spectra, fluorescence lifetimej amplification quality factors of Era+ and DSC curves of glass samples with different SiOz contents were analyzed. The results indicate that the 1.53 μm band fluorescence intensity of Era+ is im- proved when the SiOz content in the glass is 9 %(in mole} due to the enhanced energy transfer between Era+ and Ce3+ ions, and its fluorescence full width at half maximum is broadened and the thermal stability of glass host is improved accordingly with the SiOz content.