中文摘要：

利用氯化锰与4-氧-1（4H）-吡啶乙酸反应合成了-个新的配合物[Mn（H2O）6]（4-OPA）2·2H2O（4-OPA^-=4-氧-1（4H）-吡啶乙酸根），并对其进行了元素分析、IR光谱和单晶X射线的表征。配合物晶体属单斜晶系，空间群为P21／c，晶胞参数为a=1．2561（3）nm，b=1．2949（3）nm，c=0．68547（14）nm，β=98．68（3）°。V=1．1022（4）nm^3，Z=2，Mr=503．32，最终R=0．0319，ωR=0．0827。Mn（Ⅱ）原子与六个水分子配位形成八面体构型，4-氧-1（4H）-吡啶乙酸根作为抗衡阴离子。配阳离子与阴离子之间通过静电吸引和氢键作用形成了三维氢键超分子网络结构。

英文摘要：

A novel complex of [Mn（H2O）6]（4-OPA）2·2H2O （4 - OPA - = 4 - oxo - 1 （4H） - pyridineacetate ） was synthesized by the reaction MnCl2 ·4H2O and 4 -oxo -1 （4H） -pyridineacetic acid in an aqueous solution, and characterized by elemental analysis, IR spectrum and single crystal X- ray diffraction. The title complex belongs to monoclinic system with space group P21/c, a=1.2561（3）nm,b=1.2949（3）nm,c=0.68547（14）nm,β=98.68（3）°.V=1.1022（4）nm^3,Z=2,Mr=503.32. R=0.0319,ωR=0.0827 The gn（Ⅱ） atom resided in the inversion center is coordinated by six water molecules, having a nearly ideal octahedron geometry. The 4 - oxo - 1 （4H） - pyridineacetate anion acts as counter - ion. Furthermore, a three - dimensional H - bonding supramolecular framework is contrusted by intramolecule hydrogen bonds and eletrostatic interactions between the anions and cations.