欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
采用Aldol、Adler缩合、Michael加成、Vils-meier和Knoevenagel等反应合成一种新型的D-π-A型的含C∧N∧N结构的环金属化有机配体：反式-4-[2-（5,10,15,20-四苯基卟啉基）乙烯基]-N-{4-[（2-苯基-6-吡啶基）吡啶]苯甲基}吡啶溴盐（简写为TPPB）。用核磁共振氢谱、碳谱和电喷雾质谱等手段对其结构进行了表征,初步研究了该化合物的紫外-可见光谱、荧光光谱、电化学和热稳定性。结果表明目标化合物有较好的溶解性和荧光性质,为寻找新的发光材料进行了有益的探索。
英文摘要：
Efficent aqueous-phase Aldol condensation,Adler condensation,Michael addition,Vilsmeier and Knoevenagel reaction were successfully employed to synthesize a new donor-π-acceptor（D-π-A） type C∧N∧N structure of the cyclometaled organic ligand： trans-4-[2-（5,10,15,20-tetraphenylporphyrin-2-yl）-ethenyl]-N-{4-[（2-phenyl-6-pyridine）pyridium]tolyl}-pyridium bromine salt（abbreviated as TPPB）,the compound was characterized by 1H NMR,13C-NMR and ESI-MS.Linear optical,thermostability and electrochemical properties of the novel ligand were investigated.The results showed that the target molecule had good solubility and fluorescence properties which were instructive explorations for pursuing new luminescent materials.
同期刊论文项目
同项目期刊论文
Investigation of structure–property relationships of multi-branched two-photon absorption chromophor
Synthesis, Crystal Structures, Photophysical Properties, and Bioimaging of Living Cells of Bis-β-Dik
Studies of the isomerization and photophysical properties of a novel 2,2 :6,2-terpyridine-based liga
Three Asymmetrical Conjugated D-(-D Sulfur-Containing
Chromophores with a Focus on Two-Photon Absorp
Multi-carbazole derivatives for two-photon absorption data storage: synthesis, optical properties an
Four divalent metal thiocyanate coordination compounds containing a rigid functional pyridine ligand
Two-photon absorption enhancement induced by aggregation with accurate photophysical data: spontaneo
Synthesis and Properties of a meso–Tetraphenylporphyrin and its Zn (II) Complex with a dicyanoisopho
Synthesis, Characterization and in vitro antitumor activity of three organotin (IV) complexes with c
E?cient two-photon-sensitized luminescence of a novel europium(III) (-diketonate complex and applica
Synthesis, crystal structure, optical properties, DNA-binding and cell imagine of an organic chromop
Tuning the optical properties of flurophore- hexylcarbazole organic nanoribbons with dispersed inorg
Synthesis, Crystal structure, electrochemical studies and anti-tumor activities of three polynuclear
Synthesis, crystal structures and in vitro antibacterial activity of two novel organotin(IV) complex
Suppression of aggregation-induced ?uorescence quenching in pyrene derivatives: photophysical proper
A new ligand for the formation of a 3D structure by C-H…O, O-H…O hydrogen-bonds and (-( interactions
期刊信息
位置：