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Promotion of catalytic activity for methanol electro-oxidation on CoPc-Pt/C co-catalysts
  • ISSN号:1002-087X
  • 期刊名称:《电源技术》
  • 时间:0
  • 分类:O646[理学—物理化学;理学—化学] O643.36[理学—物理化学;理学—化学]
  • 作者机构:[1]State Key Laboratory of Advanced Technology for Materials Synthesis and Progressing, Wuhan University of Technology, Wuhan 430070, China
  • 相关基金:Supported by the National Natural Science Foundation of China (Grant No. 20576106)
中文摘要:

为 CoPc-Pt/C 合作催化剂上的甲醇电镀物品氧化的催化活性,由受精方法准备了,通过电气化学的方法在细节被学习。循环伏安法(CV ) 结果证明 CoPc 有更高前面的阳极的山峰电流密度和 j f /j b 价值(向前阳极的山峰水流 density/backward 阳极的山峰电流密度) 比 Pt/C。计时电流分析法(CA ) 分析显示 CoPc-Pt/C 两个都与 Pt/C 相比为甲醇电镀物品氧化展出优秀短暂电流密度和稳定的电流密度。与催化活性的提升有关的二主要机制如下:CoPc-Pt/C 举办忍耐的活动到碳的中介,因此禁止催化剂自我毒害;突出的内在的催化活性在 CoPc-Pt/C 上为甲醇氧化由明显的活化能显示了的 CoPc-Pt/C 自己,是 18 kJ/mol,不到那在是的磅和 PtRu 催化剂上报导了。

英文摘要:

The catalytic activity for methanol electro-oxidation on CoPc-Pt/C co-catalysts, prepared by impregnation method, was studied in details through electrochemical methods. Cyclic voltammetry (CV) result demonstrates that CoPc has higher forward anodic peak current density and jt/jb value (forward anodic peak current density/backward anodic peak current density) than Pt/C. Chronoamperometry (CA) analysis indicates that CoPc-Pt/C exhibits both excellent transient current density and stable current density for methanol electro-oxidation compared with Pt/C. Two main mechanisms related to the promotion of catalytic activity are as follows: CoPc-Pt/C has the activity of tolerance to carbonaceous intermediates, thus inhibiting the self-poisoning of catalysts; CoPc-Pt/C owns prominent intrinsic catalytic activity indicated by the apparent activation energy for methanol oxidation on CoPc-Pt/C, which is 18 kJ/mol, less than that on Pt and PtRu catalysts as reported.

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期刊信息
  • 《电源技术》
  • 中国科技核心期刊
  • 主管单位:中国电子科技集团公司
  • 主办单位:中国电子科技集团公司第十八研究所
  • 主编:黄永才
  • 地址:天津市西青海泰华科七路6号
  • 邮编:300384
  • 邮箱:cjps@tips.ac.cn
  • 电话:022-23959362
  • 国际标准刊号:ISSN:1002-087X
  • 国内统一刊号:ISSN:12-1126/TM
  • 邮发代号:6-28
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,连续四届天津市优秀期刊
  • 国内外数据库收录:
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  • 被引量:11796