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中文摘要：
以β-环糊精（β-CD）为原料,环氧氯丙烷（ECH）为交联剂,采用反相乳液法得到β-环糊精聚合物（β-CDP）微球,探讨了水溶液中β-CDP微球对对硝基苯酚（p-NP）吸附的动力学、热力学特性及其机理,绘制了不同温度下的吸附等温线。结果表明：β-CDP微球对p-NP的吸附2 h后基本达到平衡,且与一级吸附动力学模型和二级吸附动力学模型都有较好拟合,相关系数分别为0.9915、0.9998;在298 K、318 K和338 K温度下符合Langmiur方程和Freundlich方程;吸附焓变（ΔH）、熵变（ΔS）和吉布斯函变（ΔG）均为负值,吸附是焓推动作用,自发且过程放热。
英文摘要：
β-Cyclodextrin polyme（rβ-CDP）microspheres were synthesized from β-cyclodextri（nβ-CD） by inverse emulsion polymerization with epichlorohydrin as a crosslinking agent.Thermodynamic and kinetic characteristics as well as adsorption mechanism of β-CDP microspheres for p-nitrophenol（p-NP）from aqueous solution were investigated.Static adsorption isotherms at different temperatures illustrated that adsorption of p-NP on β-CDP microspheres reached a balance after 2h.The adsorption fitted with the first-and second-order dynamic equations,and the correlation coefficients were 0.9915 and 0.9998,respectively.The Langmiur and the Freundlich adsorption isotherm equations were adapted for the adsorption characteristics of β-CDP microspheres for p-NP at temperatures of 298 K,318 K and 338 K.The enthalpy chang（eΔH）,free energy chang（eΔG）and entropy chang（eΔS）were all negative,and the adsorption was a spontaneous,endothermic and enthalpy promoting process.
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