导电高分子聚苯胺由于其优异的电学性能而备受关注一.但由于聚苯胺分子链上缺陷较多,结构不规整,影响了对其导电机制的深入研究;由于其不溶不熔,可加工性差,阻碍了其实际应用.因此,设计并合成结构完整确定的含有苯胺链段的聚合物备受关注.
A new electroactive polyaryletherketone containing benzonitrile(EPEEK-CN) was synthesized from 2,6-difluorobenzonitrile,p-benzenediol and difluoromonomer containing phenyl-capped aniline tetramer segment,via ternary polycondensation.The obtained EPEEK-CN shows certain extent solubility in organic solvents,and its film casted from DMAc solution exhibits interesting electrical,mechanical and dielectric properties.