以5-(3-硝基苯基)二吡咯甲烷与2,4-二氯基苯甲醛或2,4-二甲氧基苯甲醛为原料,在水和甲醇溶剂中采用改进的Lindsey法合成了标题化合物,测定了化合物的紫外-可见及荧光光谱,用红外、核磁共振、质谱等技术对化合物的结构进行了表征,结果表明所得产物即为目标配合物。
Two A2 B corroles, 10- ( 2,4-dichlorophenyl ) -5,15- bis ( 3-nitrophenyl ) corrole and 10-( 2,4-dimethoxyphenyl ) - 5,15-bis (3-nitrophenyl) corrole, were synthesized using the improved Lindsey method by a reaction of 2,4-dichlorobenzal- dehyde, 2,4-dimethoxybenzaldehyde and 5-( 3-nitrophenyl ) dipyrromethane in methanol-water solutions. The UV-visible and fluorescence spectra of the synthesized corroles were measured and the structures were confirmed by FTIR, 1HNMR and MS. The results indicated that the products obtained are the target compounds.