研究白腐真菌粉末对Zn2+的吸附效果、影响因素及其吸附机理。结果表明,35min后吸附过程基本完成,pH适宜范围为5-6,Zn2+吸附率随着Zn2+初始浓度增大而提高,且在Zn2+初始浓度为25mg/L,吸附剂用量为2.5g/L,pH为5.5的最佳条件下,Zn2+吸附率达到98.01%。与原白腐真菌相比,用0.8mol/LNaOH对菌样进行预处理,Zn2+的吸附率可提高10%左右。运用扫描电镜(SEM)、X射线衍射仪(XRD)和红外光谱仪(FTIR)对Zn2+吸附前后的白腐真菌粉末进行表征。结果表明,白腐真菌表面粗糙,孔隙多。吸附Zn2+的过程中,白腐真菌表面的-OH和-PO4与Zn2+发生络合反应,生成的产物主要为磷酸锌和氢氧化锌。
Efficiencies, influence factors and absorption mechanism of Zn2+ adsorption by white rot fungi powder were investigated. Results showed that the process for adsorption of Zn2+ can be basically finished in 35 min, with suitable pH in range of 5-6, and adsorption rate of Zn2+ increased with increase of initial concentration of Zn2+. Under the optimal reaction conditions as initial concentration of Zn2+ 25 mg/L, adsorption dosage 2.5 g/L and pH value 5.5, the adsorption rate of Zn2~ was 98.01%. In comparison with the untreated fungus, the fungus treated with 0.8 mol/L NaOH solution, the adsorption rate of Zn2+can increase about 10%. The fungus surface was characterized by scanning electron microscopy, X- ray diffraction and infrared spectroscopy, results indicated that the fungus surface was rough and porous.-OH,-PO4 and Zn2+ involved in complexation reactions in the processof Zn2+ adsorption by the fungus, with main products as Zn3(PO,)2 and Zn(OH)2.