在乙醇溶剂中,采用一种新的合成方法,在马尿酸和2,2′-联吡啶两种配体共存的情况下,合成了标题化合物,通过元素分析、红外光谱对其进行了表征。并用X-射线单晶衍射方法对其进行了晶体结构解析,结果表明,该化合物为单斜晶系,晶胞为C2/c,晶胞参数:a=1.54304(14)nm,b=1.27150(11)nm,c=0.67068(5)nm,V=1.28661(19)nm^3,Z=4,Mr=353.65,Dc=1.826g/cm^3,T=298(2)K,F(000)=720,μ(MoKα)=2.098cm^-1,R=0.0229,ωR=0.0615,化合物分子通过分子间氢键和吡啶环的π-π堆积作用形成了三维网状结构。
A novel 3D network Zn(Ⅱ) complex was synthesized in ethanol solvent,and was characterized by elemental analysis and IR.The crystal structure of Zn(Ⅱ) complex was also determined by X-ray single crystal diffraction.The results showed that this Zn(Ⅱ) complex was monoclinic,with unit cell C2/c and cell parameters:a=1.543 04(14) nm,b=1.271 50(11) nm,c=0.670 68(5) nm,V=1.286 61(19) nm^3,Z=4,Mr=353.65,Dc=1.826 g/cm^3,T=298(2) K,F(000)=720,μ(MoKα)=2.098 cm^-1,R=0.022 9 and ωR=0.061 5.The compound formed 3D network network structure through intermolecular hydrogen bonds and π -π interaction of pyridine rings.