中文摘要：

合成了1，5-二（对甲氧基二苯胺）蒽（1）、2，6-二（对甲氧基二苯胺）蒽（2）和9，10-二（对甲氧基二苯胺）蒽（3）三种化合物，对它们的电化学、吸收和发射光谱、光谱电化学以及胺-胺电子耦合开展研究.三种化合物在＋0.6-＋1.0 V vs Ag/AgCl区域存在两步可逆氧化还原过程，两个氧化还原过程电位差△E在100 mV左右.单电子氧化产物1·＋在近红外区域观测到弱价间电荷转移吸收（IVCT），电子耦合常数Vab估算为600 cm-1.化合物3·＋观测到强IVCT吸收，其Vab估算为1440 cm-1.单电子氧化产物2·＋则没有观测到明显IVCT吸收，表明有机胺在蒽桥基上的取代位置对胺-胺电子耦合程度有重要的影响.

英文摘要：

Three diamine compounds with an anthracene bridge were synthesized and characterized, including 1,5-bis（di-p-anisylamine）anthracene （1）, 2,6-bis（di-p-anisylamine）anthracene （2） and 9,10-bis（di-p-anisylamine）anthracene （3）. The elec-trochemistry, absorption and emission spectra, spectroelectrochemistry, and amine-amine electronic coupling of these compounds were examined. All compounds display two consecutive redox couples in the potential region between ＋0.6 and ＋1.0 V vs Ag/AgCl, with a potential splitting △E of around 100 mV. In the one-electron-oxidized state, weak intervalence charge transfer （IVCT） transitions were observed for 1^·＋ in the near-infrared （NIR） region and the electronic coupling parameter Vab was calculated to be 600 cm^-1. In contrast, compound 3^·＋ displays an intense IVCT band in the NIR region with a Vab value of 1440 cm^-1. However, no distinct IVCT band was discernable for 2^·＋, indicative of an eligible electronic coupling. This work demonstrates that the positions of the amine substituents on the anthracene bridge play a critical role in determining the degree of amine-amine electronic coupling.