以粒径为700nm的球形Fe304为晶种,将晶种加入到含有FeS04·7H20、FeCl3·6H2O与尿素的混合溶液中,在磁场诱导下制备链状Fes04。研究了磁场强度、晶种添加量、分散剂聚乙烯吡咯烷酮(PVP)质量浓度以及反应时间对产品形貌的影响。研究结果表明,随着磁场强度的增大、晶种量的增加,链状粒子数目显著增多;适量的PVP能使链状粒子分散平行排列。合成链状Fe3O4粒子的最佳工艺条件为磁场强度0.35T,晶种用量10%,PvP质量浓度7.5g/L,反应18h。磁性能测试表明,该链状Fe304粒子具有亚铁磁性,磁饱和强度为72.3emu/g,矫顽力为381Oe。
One-dimensional chain-like magnetite particles were prepared by a seed-mediated growth method un- der the induction of magnetic field. The seeds, 700nm in size, were added into the mixture of FeSO4 · 7H20,FeCIa · 6H20 and urea. The effects of magnetic field intensity, seed amount, dispersant polyvinylpyrrolidone(PVP) concen- 0 tration and reaction time on the morphology of samples were discussed. The results showed that the number of chain- like particles increased with an increase of both magnetic field and seed amount. Appropriate PVP was favorable to ob- tain parallel chains. The optimum conditions for preparation of chain-like particles are 0. 35T magnetic field, 10% seed, 7. 5g/L PVP and 18h reaction time. Magnetic measurements reveal that magnetite chains are ferromagnetic with a saturation magnetization of 72.3emu/g and coercivity of 381Oe.