中文摘要：

利用高温熔融法分别制备了Sb3＋,Tb3＋单掺和共掺的硅酸盐发光玻璃,并分析了它们的光谱性质。根据对Sb3＋和Tb3＋掺杂硅酸盐玻璃的激发光谱、发射光谱和发光衰减时间等特性的分析,研究了澄清剂Sb2O3的加入对Tb3＋激活硅酸盐玻璃发光性能的影响。结果表明,在紫外光激发下,Tb3＋激活硅酸盐玻璃中存在Sb3＋离子至Tb3＋离子的能量传递,但能量传递效率较低,能量传递表现为Sb3＋离子的3P1能级与Tb3＋离子的5D3能级之间的能量无辐射共振转移。同时Sb3＋离子的加入将在Sb3＋离子和Tb3＋离子的激发重叠区域（200～350nm）对Tb3＋离子的激发产生不小的负面影响,尚不足以通过Sb3＋离子至Tb3＋离子的能量传递得以弥补。因此在使用Sb2O3作为Tb3＋激活硅酸盐发光玻璃的澄清剂时,应当注意权衡Sb3＋离子对Tb3＋离子发光性能的影响。

英文摘要：

The Sb3＋-doped silicate glasses, Tb3＋-doped silicate glasses, and Sb3＋ and Tb3＋ co-doped silicate glasses were syn- thesized by high-temperature melting method, and their spectral properties were analyzed. The effects of Sb2O3 added as a fining agent on the luminescent properties of Tb3＋-doped silicate glasses were studied with excitation spectra, emission spectra and decay time. The results show that there is energy transfer from Sb3＋ ions to Tb3＋ ions in the Sb3＋ and Tb3＋ co-doped silicate glasses under UV excitation, but the energy transfer efficiency between them is quite low. The energy transfer takes place between the 3P1 energy level of Sb3＋ ions and the 5D3 energy level of Tb3＋ ions in the Sb3＋ and Tbs＋ co-doped silicate glasses, and the way of the energy transfer from Sb3＋ ions to Tb3＋ ions is nonradiative energy resonance transfer. Meanwhile, introducing Sb2O3 used as a fining agent will reduce the excitation intensity of Th3＋ ions in the silicate glasses in the overlap excitation region of both Sbs＋ ions and Tb3＋ ions, which corresponds to the region from 200 to 350 nm. The reduction in the excitation intensity of Tb3＋ ions caused by introducing Sb3＋ ions is so evident that it can not be compensated by the energy transfer from Sb3＋ ions to Tb3＋ ions. Therefore, the negative effects of Sb3＋ ions on the luminescent properties of Tb3＋ ions in silicate glasses should be measured when Sb2O3 is planned to be used as a fining agent in Tb3＋-doped silicate glasses.