东篱科研大数据发现系统（DRDS）

位置：成果数据库 > 期刊 > 期刊详情页

多元改性酚醛树脂/玄武岩纤维复合材料的制备与性能

ISSN号：1000-3304
期刊名称：《高分子学报》
时间：0
分类：TQ323.1[化学工程—合成树脂塑料工业]
作者机构：[1]武汉工程大学材料科学与工程学院,湖北武汉430074, [2]北京中铁润海科技有限公司,北京100055, [3]浙江石金玄武岩纤维有限公司,浙江东阳322118
相关基金：国家自然科学基金面上项目（51373128,51173140）;武汉市科技攻关项目（2013010501010131）;地方高校国家级大学生创新创业训练计划项目（201310490011,201210490007,201210490021）;武汉工程大学第四、第五届研究生教育创新基金项目（基金号CX201231,CX201308）

作者：鄢国平[1], 黄思辰[1], 班兴明[1], 杨盛华[2], 胡斌[2], 邢晟[3]

关键词：酚醛树脂, 玄武岩纤维, 高强, 阻燃, 疏水, phenolic resin, basalt fiber, high strength, flame resistance, waterproof

中文摘要：

选用纳米二氧化硅分散液、硼酸、有机硅防水剂、七钼酸铵/季戊四醇复合阻燃剂分别对一种水溶性酚醛树脂进行改性,利用所制备的改性酚醛树脂进一步与玄武岩纤维针刺毡复合,再通过干燥、固化、定型等工艺制备复合板材,并用傅里叶红外光谱仪和示差扫描量热仪分析其结构与固化性能.结果表明,酚醛树脂与各个改性剂结合较好,改性树脂中耐高温结构增多,耐热性能得到改善.将各个改性剂进行复配、优化后提出了最佳配方,使用该配方制备的改性酚醛树脂/玄武岩纤维复合板材具有较好的机械强度与疏水性能,防火性能达到GB8624-2006的A1级标准,与同类产品综合比较优势明显,且该板材在生产加工过程中可以同步实现树脂改性与板材成型,在建筑外墙防火保温领域具有发展潜力.

英文摘要：

The modified phenolic resins were prepared by the modification of silica nanoparticles,organosilicon waterproofing agent,boric acid and hexaammonium molybdate/pentaerythrite respectively.These modified phenolic resins were further used to blend with basalt fiber needle felt to make composite boards after the drying,curing,molding process.Their structures and curing performances of modified phenolic resins were also measured by fourier infrared spectrum and differential scanning calorimetry.The experimental data show that these modified phenolic resins possess good performances,enhanced curing temperatures and good synergy; meanwhile,these composite boards have good mechanical strengths and hydrophobic properties and reach the A1 standard of GB 8624-2006.Because of the modification and shaping could be achieved in the production process simultaneously,the composite boards show the potential development in the field of flame resistance and insulation for exterior wall of the tall buildings.

同期刊论文项目

淋巴结转移性肿瘤靶向多糖类高分子正电子发射计算机断层扫描(PET)示踪剂的研究

期刊论文 8

肝癌靶向性纳米电子顺磁共振成像自旋探针及作用机理研究

期刊论文 70 会议论文 19 获奖 34 专利 2 著作 1

同项目期刊论文

Transparent Polysilicone Coatings as Protecting Films for Gold Commemorative Coins

Porphyrin Containing Isoindoline Nitroxides as Potential fluorescence Sensors of Free Radicals.

Synthesis and Properties of New pH Sensitive Chitosan Fluorescent Nanoparticles.

Sensing behaviors of polymer carbon nanotubes composites prepared in reversed microemulsion polymer

New naphthalimide modified polyethylenimine nanoparticles as fluorescent probe for DNA detection.

Preparation and properties of polycarbonate microspheres containing tetanus toxoid vaccine.

Polycarbonate magnetic microspheres containing tumor necrosis factor-α for potential targeted hepati

Synthesis and properties of non-ionic gadolinium and technetium-99m labeled complexes.

Self-assembly of polypyrrole/chitosan composite hydrogels.

A three-dimensional supramolecular framework of silver(I), 2-phenylquinoline-4-carboxylate and 4,4 &

Synthesis and ring-opening copolymerization of cyclic aryl ester dimmers.

聚碳酸酯纳米药物的制备与性能.

含卟啉基团小分子钆配合物的合成与表征.

荧光标记豇豆花叶病毒的制备及细胞成像.

聚合物纳米复合材料教学分析

Magnetic polycarbonate microspheres for tumor-targeted delivery of tumor necrosis factor

含磺胺嘧啶基团的葡聚糖钆配合物的研究.

Controlled growth of polypyrrole hydrogels

材料化学专业有机硅材料课程的设置与教学探索

碳酸酯共聚物的合成与性能

非猝灭型Cu(2+)荧光分子探针的研究进展

点击化学反应原位制备海藻酸钠水凝胶,

环状碳酸酯的微波开环共聚,

碳酸酯共聚物的合成与性能研究,

胶粉改性丁苯橡胶的制备与性能,

高分子化学与物理实验教学研究,

材料化学专业生物医用高分子课程教学探索,

构建材料化学微型实验教学体系的探索,

Fabrication and Characterization of Free-standing Polypyrrole/graphene Oxide Nanocomposite Paper,

Synthesis of a Silica Material with Surface Macroporous Arrays by a Template Method,

Polyaspartamide Spin Probes Containing Isoindoline Nitroxide and Porphyrin group.

The preparation and properties of a transparent coating based on organic silicone resins.

 Magnetic polycarbonate microspheres for tumor-targeted delivery of tumor necrosis factor.&

胶粉改性聚苯乙烯材料的制备与性能,

Bis(methanol) Tetrakis(2-phenylquinoline-4-carboxylato) Dicopper (II),

 Physical Modification of Polyetheretherke LN tone for Orthopedic Implants.

涂料与胶黏剂化学教学活动中的环境保护教育.

Synthesis and Properties of Fullerene C60 and C70Spin Probes Containing Isoindoline Nitroxi

 The preparation and properties of a transparent coating based on organic silicone resins.&

Physical Modification of Polyetheretherke LN tone for Orthopedic Implants

水溶性荧光聚合物纳米粒的制备及双光子成像.

N-氨基-4-(N-甲基哌嗪)-1,8-萘酰亚胺荧光猝灭法测定蛋白质的研究.

差示扫描量热法研究环氧端基酚酞聚芳醚酮的固化特性

Synthesis and Properties of Fullerene C60 and C70 Spin Probes Containing Isoindoline Nitroxides. ID:

含磺胺嘧啶基团的葡聚糖钆配合物的研究. 

 Tunable surface wettability and water adhesion of Sb2S3 micro-fnanorod films. 

多元改性酚醛树脂/玄武岩纤维复合材料的制备与性能. 

Preparation and Properties of Polycarbonate Microspheres Containing Tetanus Toxoid Vaccine

材料化学专业有机波谱分析课程的教学探索

Synthesis and properties of neutral gadolinium and technetium-99m labeled complexes. 

 Polycarbonate magnetic microspheres containing tumor necrosis factor-α for potential targe

 Fabrication of a new fluorescent polymeric nanoparticle containingnaphthalimide and invest

Dextran Gadolinium Complex Containing Folate Groups as aPotential Magnetic Resonance Imaging Contras

改革考试制度提高高校教学质量

高分子化学与高分子物理课程教学改革与探索

Facial Synthesis of Polyaniline/AgCl Nanocomposites at the Interface of Water and Ionic Liquid.

Dopamine-containing Gadolinium Complex as Magnetic Resonance Imaging Contrast Agent.

Synthesis and Properties of Polycarbonate Copolymers of Trimethylene Carbonate and 2-Phenyl-5,5-bis(

含磺胺嘧啶基团的葡聚糖钆配合物的研究

模压条件对EVA边角料/天然橡胶复合发泡材料性能的影响

β晶型成核剂对聚丙烯结晶行为和力学性能的影响

含卟啉基葡聚糖大分子磁共振成像造影剂的研究

偶联剂改性填料对SEBS/PP复合材料性能的影响

亚硝酸根的2,3-二氨基吩嗪荧光猝灭法测定